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The electric dipole moment is a measure of the separation of positive and negative electrical charges within a system: that is, a measure of the system's overall polarity. The SI unit for electric dipole moment is the coulomb-metre (C⋅m). The debye (D) is another unit of measurement used in atomic physics and chemistry.
An example in organic chemistry of the role of geometry in determining dipole moment is the cis and trans isomers of 1,2-dichloroethene. In the cis isomer the two polar C−Cl bonds are on the same side of the C=C double bond and the molecular dipole moment is 1.90 D.
Transition dipole moment, the electrical dipole moment in quantum mechanics; Molecular dipole moment, the electric dipole moment of a molecule. Bond dipole moment, the measure of polarity of a chemical bond; Electron electric dipole moment, the measure of the charge distribution within an electron; Magnetic dipole moment, the measure of the ...
In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole moment, with a negatively charged end and a positively charged end. Polar molecules must contain one or more polar bonds due to a difference in electronegativity between the bonded atoms.
Typical dipole moments for simple diatomic molecules are in the range of 0 to 11 D. Molecules with symmetry point groups or containing inversion symmetry will not have a permanent dipole moment, while highly ionic molecular species have a very large dipole moment, e.g. gas-phase potassium bromide, KBr, with a dipole moment of 10.41 D. [3] A proton and an electron 1 Å apart have a dipole ...
The polarizability of an atom or molecule is defined as the ratio of its induced dipole moment to the local electric field; in a crystalline solid, one considers the dipole moment per unit cell. [1] Note that the local electric field seen by a molecule is generally different from the macroscopic electric field that would be measured externally.
In organic chemistry, a dipolar compound or simply dipole is an electrically neutral molecule carrying a positive and a negative charge in at least one canonical description. In most dipolar compounds the charges are delocalized . [ 1 ]
The transition dipole moment is useful for determining if transitions are allowed under the electric dipole interaction. For example, the transition from a bonding π {\displaystyle \pi } orbital to an antibonding π ∗ {\displaystyle \pi ^{*}} orbital is allowed because the integral defining the transition dipole moment is nonzero.