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Iron–sulfur clusters are molecular ensembles of iron and sulfide. They are most often discussed in the context of the biological role for iron–sulfur proteins , which are pervasive. [ 2 ] Many Fe–S clusters are known in the area of organometallic chemistry and as precursors to synthetic analogues of the biological clusters.
Download as PDF; Printable version; In other projects ... Iron sulfide or Iron sulphide can refer to range of chemical compounds composed of iron and sulfur. Minerals
Iron sulfides occur widely in nature in the form of iron–sulfur proteins. As organic matter decays under low-oxygen (or hypoxic ) conditions such as in swamps or dead zones of lakes and oceans, sulfate-reducing bacteria reduce various sulfates present in the water, producing hydrogen sulfide .
The resulting solid decays at a temperature over 20 °C into iron(II) sulfide (FeS) and elemental sulfur: [3] Fe 2 S 3 → 2 FeS + S. With hydrochloric acid it decays according to the following reaction equation: [4] Fe 2 S 3 + 4 HCl → 2 FeCl 2 + 2 H 2 S + S
Iron(II,III) sulfide is a blue-black (sometimes pinkish [citation needed]) chemical compound of iron and sulfur with formula Fe 3 S 4 or FeS·Fe 2 S 3, which is much similar to iron(II,III) oxide. It occurs naturally as the sulfide mineral greigite and is magnetic. It is a bio-mineral produced by and found in magnetotactic bacteria.
The original paper by Ellingham explicitly to the reduction of both oxygen and sulfur by metallurgical processes, [1] and anticipated the use of such diagrams for other compounds, including chlorides, carbides, and sulfates. The concept is generally useful for studying the comparative stability of compounds across a range of partial pressures ...
Mössbauer spectroscopy has been widely applied to bioinorganic chemistry, especially for the study of iron-containing proteins and enzymes. Often the technique is used to determine the oxidation state of iron. Examples of prominent iron-containing biomolecules are iron-sulfur proteins, ferritin, and hemes including the cytochromes. These ...
Sulfur polycations, S 8 2+, S 4 2+ and S 16 2+ are produced when sulfur is reacted with oxidising agents in a strongly acidic solution. [1] The colored solutions produced by dissolving sulfur in oleum were first reported as early as 1804 by C.F. Bucholz, but the cause of the color and the structure of the polycations involved was only ...