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The relationship between chemistry and physics is a topic of debate in the philosophy of science. The issue is a complicated one, since both physics and chemistry are divided into multiple subfields, each with their own goals. A major theme is whether, and in what sense, chemistry can be said to "reduce" to physics. [1][2]
Linearity. The Schrödinger equation is a linear differential equation, meaning that if two state vectors and are solutions, then so is any linear combination of the two state vectors where a and b are any complex numbers. [13]: 25 Moreover, the sum can be extended for any number of state vectors.
Quantum mechanics is a fundamental theory that describes the behavior of nature at and below the scale of atoms. [2]: 1.1 It is the foundation of all quantum physics, which includes quantum chemistry, quantum field theory, quantum technology, and quantum information science. Quantum mechanics can describe many systems that classical physics cannot.
t. e. Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mechanics, analytical dynamics and chemical equilibria. Physical chemistry, in contrast to chemical ...
Chemical physics is a branch of physics that studies chemical processes from a physical point of view. It focuses on understanding the physical properties and behavior of chemical systems, using principles from both physics and chemistry. This field investigates physicochemical phenomena using techniques from atomic and molecular physics and ...
Perturbation theory (quantum mechanics) In quantum mechanics, perturbation theory is a set of approximation schemes directly related to mathematical perturbation for describing a complicated quantum system in terms of a simpler one. The idea is to start with a simple system for which a mathematical solution is known, and add an additional ...
t. e. The second law of thermodynamics is a physical law based on universal empirical observation concerning heat and energy interconversions. A simple statement of the law is that heat always flows spontaneously from hotter to colder regions of matter (or 'downhill' in terms of the temperature gradient).
The chemical potential of a species in a mixture is defined as the rate of change of free energy of a thermodynamic system with respect to the change in the number of atoms or molecules of the species that are added to the system. Thus, it is the partial derivative of the free energy with respect to the amount of the species, all other species ...