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Amperometric titration refers to a class of titrations in which the equivalence point is determined through measurement of the electric current produced by the titration reaction. It is a form of quantitative analysis .
A chloridometer is a measuring instrument used to determine the concentration of chloride ions (Cl –) in a solution.It uses a process known as coulometric titration or amperostatic coulometry, the accepted electrochemistry reference method to determine the concentration of chloride in biological fluids, including blood serum, blood plasma, urine, sweat, and cerebrospinal fluid.
Any analyte that can be oxidized or reduced is a candidate for amperometric detection. The simplest form of amperometric detection is single-potential, or direct current (DC), amperometry. A voltage (potential) is applied between two electrodes positioned in the column effluent. The measured current changes as an electroactive analyte is ...
This method, in practical terms, is non-destructive since only a very small amount of the analyte is consumed at the two-dimensional surface of the working and auxiliary electrodes. In practice, the analyte solution is usually disposed of since it is difficult to separate the analyte from the bulk electrolyte , and the experiment requires a ...
The Mohr method may be adapted to determine the total chlorine content of a sample by igniting the sample with calcium, then ferric acetate. Calcium acetate "fixes" free chlorine, precipitates carbonates, and neutralizes the resultant solution. Ferric acetate removes phosphates. All chlorides are dissolved out of the residue, and titrated. [1]
Advantages of Coulometric Titration Coulometric titration has the advantage that constant current sources for the generation of titrants are relatively easy to make. The electrochemical generation of a titrant is much more sensitive and can be much more accurately controlled than the mechanical addition of titrant using a burette drive.