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Fe 2 O 3 structure. Two other examples of commonly-encountered chemicals are Fe 2 O 3 and TiO 2. Fe 2 O 3 has a crystal structure that can be described as having a near close packed array of oxygen atoms with iron atoms filling two thirds of the octahedral holes. However each iron atom has 3 nearest neighbors and 3 others a little further away.
This naming has been developed principally for coordination compounds although it can be more widely applied. Examples are: Si(OH) 4 tetrahydroxidosilicon (additive), or silanetetrol (substitutive) (note silicic acid is an acceptable name—orthosilicic has been dropped). [CoCl(NH 3) 5]Cl 2 pentaamminechloridocobalt(2+) chloride
IUPAC states that, "As one of its major activities, IUPAC develops Recommendations to establish unambiguous, uniform, and consistent nomenclature and terminology for specific scientific fields, usually presented as: glossaries of terms for specific chemical disciplines; definitions of terms relating to a group of properties; nomenclature of chemical compounds and their classes; terminology ...
The main purpose of chemical nomenclature is to disambiguate the spoken or written names of chemical compounds: each name should refer to one compound. Secondarily, each compound should have only one name, although in some cases some alternative names are accepted. Preferably, the name should also represent the structure or chemistry of a compound.
Cisplatin, PtCl 2 (NH 3) 2, is a coordination complex of platinum(II) with two chloride and two ammonia ligands.It is one of the most successful anticancer drugs. A coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands ...
The number of coordination bonds (coordination number) can vary from two in K[Ag(CN) 2] as high as 20 in Th(η 5-C 5 H 5) 4. [ 2 ] One of the most common coordination geometries is octahedral , where six ligands are coordinated to the metal in a symmetrical distribution, leading to the formation of an octahedron if lines were drawn between the ...
In common usage, the prefix dipolar, dative or coordinate merely serves to indicate the origin of the electrons used in creating the bond. For example, F 3 B ← O(C 2 H 5) 2 ("boron trifluoride (diethyl) etherate") is prepared from BF 3 and :O(C 2 H 5) 2, as opposed to the radical species [•BF 3] – and [•O(C 2 H 5) 2] +.
This page provides a list of chemicals which are coordination compounds and complex salts in nature. Subcategories. This category has the following 34 subcategories ...