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Rhodium trichloride and its various hydrates can be considered the default halides of rhodium. By contrast, its lighter congener cobalt does not form a stable trichloride, mainly being available as cobalt(II) chloride. Anhydrous rhodium chloride is a dense red-brown solid.
Organorhodium chemistry is the chemistry of organometallic compounds containing a rhodium-carbon chemical bond, and the study of rhodium and rhodium compounds as catalysts in organic reactions. [ 1 ] Stable organorhodium compounds and transient organorhodium intermediates are used as catalyst such as in olefin hydroformylation , olefin ...
Hydrated rhodium trichloride is reduced by carbon monoxide, ethylene, and trifluorophosphine to give rhodium(I) complexes Rh 2 Cl 2 L 4 (L = CO, C 2 H 4, PF 3). When treated with triphenylphosphine, hydrated rhodium trichloride converts to the maroon-colored RhCl(P(C 6 H 5) 3) 3, which is known as Wilkinson's catalyst.
It is a yellow, water-soluble solid. The salt is an intermediate in the purification of rhodium from its ores. As shown by X-ray crystallography, the salt consists of the octahedral complex [RhCl(NH 3) 5] 2+ and two chloride counterions. [1] It forms from the reaction of rhodium trichloride and ammonia in ethanol. [2]
Trichloride may refer to: The trichloride ion, a polyhalogen ion; ... Rhodium trichloride, RhCl 3; Ruthenium trichloride, RuCl 3; Samarium trichloride, SmCl 3;
Rhodium carbonyl chloride is an organorhodium compound with the formula Rh 2 Cl 2 (CO) 4. It is a red-brown volatile solid that is soluble in nonpolar organic solvents. It is a precursor to other rhodium carbonyl complexes, some of which are useful in homogeneous catalysis.
Cyclooctadiene rhodium chloride dimer is the organorhodium compound with the formula Rh 2 Cl 2 (C 8 H 12) 2, commonly abbreviated [RhCl(COD)] 2 or Rh 2 Cl 2 (COD) 2. This yellow-orange, air-stable compound is a widely used precursor to homogeneous catalysts .
Chlorobis(cyclooctene)rhodium dimer; Chlorobis(dppe)iron hydride; Chlorobis(ethylene)rhodium dimer; Chloropentammineplatinum chloride; Cis-Dichlorobis(bipyridine)ruthenium(II) Cisplatin; Cyclooctadiene iridium chloride dimer; Cyclooctadiene rhodium chloride dimer (Cyclopentadienyl)titanium trichloride (Cyclopentadienyl)zirconium trichloride