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The circumstances under which a compound will have ionic or covalent character can typically be understood using Fajans' rules, which use only charges and the sizes of each ion. According to these rules, compounds with the most ionic character will have large positive ions with a low charge, bonded to a small negative ion with a high charge. [25]
The only metal having an ionisation energy higher than some nonmetals (sulfur and selenium) is mercury. [citation needed] Mercury and its compounds have a reputation for toxicity but on a scale of 1 to 10, dimethylmercury ((CH 3) 2 Hg) (abbr. DMM), a volatile colourless liquid, has been described as a 15. It is so dangerous that scientists have ...
In ionic compounds there arise characteristic distances between ion neighbours from which the spatial extension and the ionic radius of individual ions may be derived. The most common type of ionic bonding is seen in compounds of metals and nonmetals (except noble gases, which rarely form chemical compounds). Metals are characterized by having ...
All four elements tend to form primarily ionic compounds with metals, [136] in contrast to the remaining nonmetals (except for oxygen) which tend to form primarily covalent compounds with metals. [ x ] The highly reactive and strongly electronegative nature of the halogen nonmetals epitomizes nonmetallic character.
Nonmetals, including (to a limited extent) xenon and probably radon, usually exist as anions or oxyanions in aqueous solution; they generally form ionic or covalent compounds when combined with metals (unlike metals, which mostly form alloys with other metals); and have acidic oxides whereas the common oxides of nearly all metals are basic.
In the simplest case, the cation is a metal atom and the anion is a nonmetal atom, but these ions can be more complex, e.g. polyatomic ions like NH + 4 or SO 2− 4. In simpler words, an ionic bond results from the transfer of electrons from a metal to a non-metal to obtain a full valence shell for both atoms.
For example, "ferrous sulfide" can refer to the 1:1 species (mineral name troilite) or a host of Fe-deficient derivatives . The mineral magnetite ("lode stone") is a mixed-valence compound with both Fe(II) and Fe(III), Fe 3 O 4.
Arsenic reacts with metals to form arsenides, though these are not ionic compounds containing the As 3− ion as the formation of such an anion would be highly endothermic and even the group 1 arsenides have properties of intermetallic compounds. [31]