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Boron trioxide or diboron trioxide is the oxide of boron with the formula B 2 O 3. It is a colorless transparent solid, almost always glassy (amorphous), which can be crystallized only with great difficulty.
Guitar slide made of borosilicate glass. Borosilicate glass is a type of glass with silica and boron trioxide as the main glass-forming constituents. Borosilicate glasses are known for having very low coefficients of thermal expansion (≈3 × 10 −6 K −1 at 20 °C), making them more resistant to thermal shock than any other common glass.
Often the boron in borides has fractional oxidation states, such as −1/3 in calcium hexaboride (CaB 6). From the structural perspective, the most distinctive chemical compounds of boron are the hydrides. Included in this series are the cluster compounds dodecaborate (B 12 H 2− 12), decaborane (B 10 H 14), and the carboranes such as C 2 B 10 ...
[16] [17] [18] However, some of its behaviour towards some chemical reactions suggest it to be a tribasic acid in the Brønsted-Lowry sense as well. Boric acid, mixed with borax Na 2 B 4 O 7 ·10H 2 O (more properly Na 2 B 4 O 5 (OH) 4 ·8H 2 O ) in the weight ratio of 4:5, is highly soluble in water, though they are not so soluble separately.
Boron oxide may refer to one of several oxides of boron: Boron trioxide (B 2 O 3, diboron trioxide), the most common form;
The reaction is much slower with ketones than aldehydes. [40] For example, in Nicolaou's epothilones synthesis, asymmetric allylboration (with an allylborane derived from chiral alpha-pinene) is the first step in a two-carbon homologation to acetogenin: [41] Trifluoroborate salts are stabler than boronic acids and selectively alkylate aldehydes ...
It is formed by the reaction of boric acid and ethanol in the presence of acid catalyst, where it forms according to the equilibrium reaction: B(OH) 3 + 3 C 2 H 5 OH ⇌ (C 2 H 5 O) 3 B + 3 H 2 O. In order to increase the rate of forward reaction, the formed water must be removed from reaction media by either azeotropic distillation or adsorption.
The boron group is notable for trends in the electron configuration, as shown above, and in some of its elements' characteristics. Boron differs from the other group members in its hardness, refractivity and reluctance to participate in metallic bonding. An example of a trend in reactivity is boron's tendency to form reactive compounds with ...