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Boron trioxide or diboron trioxide is the oxide of boron with the formula B 2 O 3. It is a colorless transparent solid, almost always glassy (amorphous), which can be crystallized only with great difficulty.
Boron oxide may refer to one of several oxides of boron: Boron trioxide (B 2 O 3, diboron trioxide), the most common form;
An oxide (/ ˈ ɒ k s aɪ d /) is a chemical compound containing at least one oxygen atom and one other element [1] in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of –2) of oxygen, an O 2– ion with oxygen in the oxidation state of −2.
Guitar slide made of borosilicate glass. Borosilicate glass is a type of glass with silica and boron trioxide as the main glass-forming constituents. Borosilicate glasses are known for having very low coefficients of thermal expansion (≈3 × 10 −6 K −1 at 20 °C), making them more resistant to thermal shock than any other common glass.
It is formed by the reaction of boric acid and ethanol in the presence of acid catalyst, where it forms according to the equilibrium reaction: B(OH) 3 + 3 C 2 H 5 OH ⇌ (C 2 H 5 O) 3 B + 3 H 2 O. In order to increase the rate of forward reaction, the formed water must be removed from reaction media by either azeotropic distillation or adsorption.
The reaction of boron trichloride with alcohols was reported in 1931, and was used to prepare dimethoxyboron chloride, B(OCH 3) 2 Cl. [3] Egon Wiberg and Wilhelm Ruschmann used it to prepare tetrahydroxydiboron by first introducing the boron–boron bond by reduction with sodium and then hydrolysing the resulting tetramethoxydiboron, B 2 (OCH 3) 4, to produce what they termed sub-boric acid. [4]
This page provides supplementary chemical data on boron trioxide. Material Safety Data Sheet. MSDS from SIRI; Structure and properties. Structure and properties Index ...
The Parikh–Doering oxidation is an oxidation reaction that transforms primary and secondary alcohols into aldehydes and ketones, respectively. [1] The procedure uses dimethyl sulfoxide (DMSO) as the oxidant and the solvent, activated by the sulfur trioxide pyridine complex (SO 3 •C 5 H 5 N) in the presence of triethylamine or diisopropylethylamine as base.