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Substituting into the Clapeyron equation =, we can obtain the Clausius–Clapeyron equation [8]: 509 = for low temperatures and pressures, [8]: 509 where is the specific latent heat of the substance. Instead of the specific, corresponding molar values (i.e. L {\\displaystyle L} in kJ/mol and R = 8.31 J/(mol⋅K)) may also be used.
Ehrenfest equations (named after Paul Ehrenfest) are equations which describe changes in specific heat capacity and derivatives of specific volume in second-order phase transitions. The Clausius–Clapeyron relation does not make sense for second-order phase transitions, [ 1 ] as both specific entropy and specific volume do not change in second ...
The Antoine equation is a class of semi-empirical correlations describing the relation between vapor pressure and temperature for pure substances. The Antoine equation is derived from the Clausius–Clapeyron relation. The equation was presented in 1888 by the French engineer Louis Charles Antoine (1825–1897). [1]
The Antoine equation [3] [4] is a pragmatic mathematical expression of the relation between the vapor pressure and the temperature of pure liquid or solid substances. It is obtained by curve-fitting and is adapted to the fact that vapor pressure is usually increasing and concave as a function of temperature.
In the linear theory of elasticity Clapeyron's theorem states that the potential energy of deformation of a body, which is in equilibrium under a given load, is equal to half the work done by the external forces computed assuming these forces had remained constant from the initial state to the final state. [1]
He used the now abandoned unit 'Clausius' (symbol: Cl) for entropy. [17] 1 Clausius (Cl) = 1 calorie/degree Celsius (cal/°C) = 4.1868 joules per kelvin (J/K) The landmark 1865 paper in which he introduced the concept of entropy ends with the following summary of the first and second laws of thermodynamics: [4] The energy of the universe is ...