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Metallurgical coal or coking coal [1] is a grade of coal that can be used to produce good-quality coke. Coke is an essential fuel and reactant in the blast furnace process for primary steelmaking. [2] [3] [4] The demand for metallurgical coal is highly coupled to the demand for steel. Primary steelmaking companies often have a division that ...
Coking is the process of heating coal in the absence of oxygen to a temperature above 600 °C (1,112 °F) to drive off the volatile components of the raw coal, leaving behind a hard, strong, porous material with a high carbon content called coke. Coke is predominantly carbon.
This removes high-ash value particle and increases the saleability of the coal as well as its energy content per unit volume. Thus, coals must be subjected to a float-sink test in the laboratory, which will determine the optimum particle size for washing, the density of the wash liquid required to remove the maximum ash value with the minimum work.
Some facilities have "by-product" coking ovens in which the volatile decomposition products are collected, purified and separated for use in other industries, as fuel or chemical feedstocks. Otherwise the volatile byproducts are burned to heat the coking ovens. This is an older method, but is still being used for new construction. [5]
The coke-making or "coking" process consists of heating the material in "coking ovens" to very high temperatures (up to 900 °C or 1,700 °F) so that the molecules are broken down into lighter volatile substances, which leave the vessel, and a porous but hard residue that is mostly carbon and inorganic ash.
As petcoke has a higher energy content, petcoke emits between 30% and 80% more CO 2 than coal per unit of weight. [3] The difference between coal and coke in CO 2 production per unit of energy produced depends upon the moisture in the coal, which increases the CO 2 per unit of energy – heat of combustion – and on the volatile hydrocarbons ...
Breaking and making chemical bonds involves energy release or uptake, often as heat that may be either absorbed by or evolved from the chemical system. Energy released (or absorbed) because of a reaction between chemical substances ("reactants") is equal to the difference between the energy content of the products and the reactants.
A coking factory or a coking plant is where coke and manufactured gas are synthesized from coal using a dry distillation process. The volatile components of the pyrolyzed coal, released by heating to a temperature of between 900°C and 1,400 °C, are generally drawn off and recovered. There are also coking plants where the released components ...