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Conductivity or specific conductance of an electrolyte solution is a measure of its ability to conduct electricity. The SI unit of conductivity is siemens per meter (S/m). Conductivity measurements are used routinely in many industrial and environmental applications as a fast, inexpensive and reliable way of measuring the ionic content in a ...
The conductivity of a water/aqueous solution is highly dependent on its concentration of dissolved salts, and other chemical species that ionize in the solution. Electrical conductivity of water samples is used as an indicator of how salt-free, ion-free, or impurity-free the sample is; the purer the water, the lower the conductivity (the higher ...
For weak electrolytes (i.e. incompletely dissociated electrolytes), however, the molar conductivity strongly depends on concentration: The more dilute a solution, the greater its molar conductivity, due to increased ionic dissociation. For example, acetic acid has a higher molar conductivity in dilute aqueous acetic acid than in concentrated ...
In usual analytical chemistry practice, the term conductometry is used as a synonym of conductometric titration while the term conductimetry is used to describe non-titrative applications. [1] Conductometry is often applied to determine the total conductance of a solution or to analyze the end point of titrations that include ions. [2]
For example, in an aqueous solution of sodium chloride, less than half of the current is carried by the positively charged sodium ions (cations) and more than half is carried by the negatively charged chloride ions (anions) because the chloride ions are able to move faster, i.e., chloride ions have higher mobility than sodium ions. The sum of ...
In this case, the carrier density (in this context, also called the free electron density) can be estimated by: [5] n = N A Z ρ m m a {\displaystyle n={\frac {N_{\text{A}}Z\rho _{m}}{m_{a}}}} Where N A {\displaystyle N_{\text{A}}} is the Avogadro constant , Z is the number of valence electrons , ρ m {\displaystyle \rho _{m}} is the density of ...
In 1921, solid silver iodide (AgI) was found to have had extraordinary high ionic conductivity at temperatures above 147 °C, AgI changes into a phase that has an ionic conductivity of ~ 1 –1 cm −1. [clarification needed] This high temperature phase of AgI is an example of a superionic conductor.
For example, the mobility of the sodium ion (Na +) in water at 25 °C is 5.19 × 10 −8 m 2 /(V·s). [1] This means that a sodium ion in an electric field of 1 V/m would have an average drift velocity of 5.19 × 10 −8 m/s. Such values can be obtained from measurements of ionic conductivity in solution.