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The van Deemter equation is a hyperbolic function that predicts that there is an optimum velocity at which there will be the minimum variance per unit column length and, thence, a maximum efficiency. The van Deemter equation was the result of the first application of rate theory to the chromatography elution process.
Isothermal Kovats index is independent of , any GC dimension or ß or carrier gas velocity , which compares favorable to retention time . Isothermal Kovats index is based on solubility S i {\displaystyle S_{i}} and vapor pressure P i {\displaystyle P^{i}} of compound i and n -Alkanes ( i = n {\displaystyle i=n} ).
In engineering and physics, g c is a unit conversion factor used to convert mass to force or vice versa. [1] It is defined as = In unit systems where force is a derived unit, like in SI units, g c is equal to 1.
The tangential arrow represents the tangential linear velocity (m/min or sfm) at the outer diameter of the cutter, called the "cutting speed", "surface speed", or simply the "speed" by machinists. The arrow colinear with the slot that has been milled represents the linear velocity at which the cutter is advanced laterally (usually mm/min or ...
The linear motion can be of two types: uniform linear motion, with constant velocity (zero acceleration); and non-uniform linear motion, with variable velocity (non-zero acceleration). The motion of a particle (a point-like object) along a line can be described by its position x {\displaystyle x} , which varies with t {\displaystyle t} (time).
Chromatographic peak resolution is given by = + where t R is the retention time and w b is the peak width at baseline. The bigger the time-difference and/or the smaller the bandwidths, the better the resolution of the compounds.
The Stokes drift velocity ū S, which is the particle drift after one wave cycle divided by the period, can be estimated using the results of linear theory: [38] u ¯ S = 1 2 σ k a 2 cosh 2 k ( z + h ) sinh 2 k h e k , {\displaystyle {\bar {\mathbf {u} }}_{S}={\tfrac {1}{2}}\sigma ka^{2}{\frac {\cosh 2k(z+h)}{\sinh ^{2}kh}}\mathbf {e ...
In the linear case the flux and the force are said to be conjugate to each other. The relation between a thermodynamic force F and its conjugate thermodynamic flux J is called a linear constitutive relation, = (=). L(0) is called a linear transport coefficient. In the case of multiple forces and fluxes acting simultaneously, the fluxes and ...