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The van Deemter equation is a hyperbolic function that predicts that there is an optimum velocity at which there will be the minimum variance per unit column length and, thence, a maximum efficiency. The van Deemter equation was the result of the first application of rate theory to the chromatography elution process.
In engineering and physics, g c is a unit conversion factor used to convert mass to force or vice versa. [1] It is defined as = In unit systems where force is a derived unit, like in SI units, g c is equal to 1.
As a simple approximate equation, the physical value of is usually very close to 1/3 of the detonation velocity of the explosive material for standard explosives. [1] For a typical set of military explosives, the value of D 2 E {\displaystyle {\frac {D}{\sqrt {2E}}}} ranges from between 2.32 for Tritonal and 3.16 for PAX-29n.
Quantity (common name/s) (Common) symbol/s Defining equation SI units Dimension Flow velocity vector field : u = (,) m s −1 [L][T] −1 Velocity pseudovector field : ω = s −1 [T] −1 ...
The components of the sample move through the column, each at a different velocity, which are a function of specific physical interactions with the adsorbent, the stationary phase. The velocity of each component depends on its chemical nature, on the nature of the stationary phase (inside the column) and on the composition of the mobile phase.
The tangential arrow represents the tangential linear velocity (m/min or sfm) at the outer diameter of the cutter, called the "cutting speed", "surface speed", or simply the "speed" by machinists. The arrow colinear with the slot that has been milled represents the linear velocity at which the cutter is advanced laterally (usually mm/min or ...
A twist is a screw used to represent the velocity of a rigid body as an angular velocity around an axis and a linear velocity along this axis. All points in the body have the same component of the velocity along the axis, however the greater the distance from the axis the greater the velocity in the plane perpendicular to this axis.
Isothermal Kovats index is independent of , any GC dimension or ß or carrier gas velocity , which compares favorable to retention time . Isothermal Kovats index is based on solubility S i {\displaystyle S_{i}} and vapor pressure P i {\displaystyle P^{i}} of compound i and n -Alkanes ( i = n {\displaystyle i=n} ).