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In chemistry, IUPAC changed its definition of standard temperature and pressure in 1982: [1] [2] Until 1982, STP was defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute pressure of exactly 1 atm (101.325 kPa).
A millimetre of mercury is a manometric unit of pressure, formerly defined as the extra pressure generated by a column of mercury one millimetre high. Currently, it is defined as exactly 133.322 387 415 pascals, or approximately [a] 1 torr = 1 / 760 atmosphere = 101 325 / 760 pascals. [1] [2] It is denoted mmHg [3] or mm Hg. [4] [2]
Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
P S = Standard pressure (100 kPa or 750 mmHg) P water S = Partial pressure of water in saturated air (that is, at 100% relative humidity; in this case the partial pressure is equal to the vapour pressure, which can be determined as a function of ambient temperature) P water B = Partial pressure of water in saturated air in 37 °C = 47 mmHg
A typical phase diagram.The solid green line applies to most substances; the dashed green line gives the anomalous behavior of water. In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium. [1]
The standard atmosphere was originally defined as the pressure exerted by a 760 mm column of mercury at 0 °C (32 °F) and standard gravity (g n = 9.806 65 m/s 2). [2] It was used as a reference condition for physical and chemical properties, and the definition of the centigrade temperature scale set 100 °C as the boiling point of water at this pressure.
The standard state of a material (pure substance, mixture or solution) is a reference point used to calculate its properties under different conditions.A degree sign (°) or a superscript Plimsoll symbol (⦵) is used to designate a thermodynamic quantity in the standard state, such as change in enthalpy (ΔH°), change in entropy (ΔS°), or change in Gibbs free energy (ΔG°).
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...