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Ammonium iron(II) sulfate, or Mohr's salt, is the inorganic compound with the formula (NH 4) 2 SO 4 ·Fe(SO 4)·6H 2 O.Containing two different cations, Fe 2+ and NH + 4, it is classified as a double salt of ferrous sulfate and ammonium sulfate.
As a salt of a strong acid (H 2 SO 4) and weak base (NH 3), its solution is acidic; the pH of 0.1 M solution is 5.5. In aqueous solution the reactions are those of NH + 4 and SO 2− 4 ions. For example, addition of barium chloride, precipitates out barium sulfate. The filtrate on evaporation yields ammonium chloride.
For example, water has a molar mass of 18.0153(3) g/mol, but individual water molecules have molecular masses which range between 18.010 564 6863 (15) Da (1 H 2 16 O) and 22.027 7364 (9) Da (2 H 2 18 O). The distinction between molar mass and molecular mass is important because relative molecular masses can be measured directly by mass ...
Copper(II) sulfate is an inorganic compound with the chemical formula Cu SO 4.It forms hydrates CuSO 4 ·nH 2 O, where n can range from 1 to 7. The pentahydrate (n = 5), a bright blue crystal, is the most commonly encountered hydrate of copper(II) sulfate, [10] while its anhydrous form is white. [11]
Ammonium iron(III) sulfate, NH 4 Fe(SO 4) 2 ·12 H 2 O, or NH 4 [Fe(H 2 O) 6](SO 4) 2 ·6 H 2 O, also known as ferric ammonium sulfate (FAS) or iron alum, is a double salt in the class of alums, which consists of compounds with the general formula AB(SO 4) 2 · 12 H 2 O. [2] It has the appearance of weakly violet, octahedrical crystals.
Ammonium persulfate (APS) is the inorganic compound with the formula (NH 4) 2 S 2 O 8. It is a colourless (white) salt that is highly soluble in water, much more so than the related potassium salt. It is a strong oxidizing agent that is used as a catalyst in polymer chemistry, as an etchant, and as a cleaning and bleaching agent. [1]
2 NH 3 + SO 2 + H 2 O → (NH 4) 2 SO 3. Ammonium sulfite is produced in gas scrubbers, now obsolete, consisting of ammonium hydroxide to remove sulfur dioxide from emissions from power plants. The conversion is the basis of the Walther Process. The resulting ammonium sulfite can be air oxidized to give ammonium sulfate. [4]
The latter is produced by the hydrogenation of nitric oxide using a platinum catalyst: [2] 2 NO + 3 H 2 + H 2 SO 4 → [NH 3 OH] 2 [SO 4] Another route to NH 2 OH is the Raschig process: aqueous ammonium nitrite is reduced by HSO − 3 and SO 2 at 0 °C to yield a hydroxylamido-N,N-disulfonate anion:: [3] [NH 4] + [NO 2] − + 2 SO 2 + NH 3 + H ...