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Acrylonitrile is an organic compound with the formula CH 2 CHCN and the structure H 2 C=CH−C≡N. It is a colorless, volatile liquid although commercial samples can be yellow due to impurities . It has a pungent odor of garlic or onions. [ 4 ]
The Pinner reaction refers to the acid catalysed reaction of a nitrile with an alcohol to form an imino ester salt (alkyl imidate salt); this is sometimes referred to as a Pinner salt. [1] The reaction is named after Adolf Pinner , who first described it in 1877.
Lewis structure of a water molecule. Lewis structures – also called Lewis dot formulas, Lewis dot structures, electron dot structures, or Lewis electron dot structures (LEDs) – are diagrams that show the bonding between atoms of a molecule, as well as the lone pairs of electrons that may exist in the molecule.
The main industrial route to this nitrile is the hydrogenation of acrylonitrile. It is also prepared by the ammoxidation of propanol (propionaldehyde can also be used instead): [7] CH 3 CH 2 CH 2 OH + O 2 + NH 3 → CH 3 CH 2 C≡N + 3 H 2 O. Propionitrile is a byproduct of the electrodimerisation of acrylonitrile to adiponitrile.
Acrylonitrile is commonly employed as a comonomer with styrene, e.g. acrylonitrile, styrene and acrylate plastics. Labelling of items of clothing with acrylic (see acrylic fiber) means the polymer consists of at least 85% acrylonitrile as the monomer. A typical comonomer is vinyl acetate, which can be solution-spun readily to obtain fibers that ...
Chemical structure of the vinyl functional group. In organic chemistry , a vinyl group (abbr. Vi ; [ 1 ] IUPAC name : ethenyl group [ 2 ] ) is a functional group with the formula −CH=CH 2 . It is the ethylene (IUPAC name: ethene) molecule ( H 2 C=CH 2 ) with one fewer hydrogen atom.
The term alcohol originally referred to the primary alcohol ethanol (ethyl alcohol), which is used as a drug and is the main alcohol present in alcoholic drinks. The suffix -ol appears in the International Union of Pure and Applied Chemistry (IUPAC) chemical name of all substances where the hydroxyl group is the functional group with the ...
The donor number is a measure of the ability of a solvent to solvate cations and Lewis acids. The method was developed by V. Gutmann in 1976. [2] Likewise Lewis acids are characterized by acceptor numbers (AN, see Gutmann–Beckett method). Typical solvent values are: [3] acetonitrile 14.1 kcal/mol (59.0 kJ/mol) acetone 17 kcal/mol (71 kJ/mol)