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  2. Critical point (thermodynamics) - Wikipedia

    en.wikipedia.org/wiki/Critical_point...

    The commonly known phases solid, liquid and vapor are separated by phase boundaries, i.e. pressuretemperature combinations where two phases can coexist. At the triple point, all three phases can coexist. However, the liquid–vapor boundary terminates in an endpoint at some critical temperature T c and critical pressure p c. This is the ...

  3. Phase diagram - Wikipedia

    en.wikipedia.org/wiki/Phase_diagram

    The critical point remains a point on the surface even on a 3D phase diagram. An orthographic projection of the 3D p–v–T graph showing pressure and temperature as the vertical and horizontal axes collapses the 3D plot into the standard 2D pressuretemperature diagram. When this is done, the solid–vapor, solid–liquid, and liquid ...

  4. Phase transition - Wikipedia

    en.wikipedia.org/wiki/Phase_transition

    In any system containing liquid and gaseous phases, there exists a special combination of pressure and temperature, known as the critical point, at which the transition between liquid and gas becomes a second-order transition. Near the critical point, the fluid is sufficiently hot and compressed that the distinction between the liquid and ...

  5. Thermodynamic diagrams - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_diagrams

    Consider a gas in cylinder with a free floating piston resting on top of a volume of gas V 1 at a temperature T 1. If the gas is heated so that the temperature of the gas goes up to T 2 while the piston is allowed to rise to V 2 as in Figure 1, then the pressure is kept the same in this process due to the free floating piston being allowed to ...

  6. Compressibility factor - Wikipedia

    en.wikipedia.org/wiki/Compressibility_factor

    As temperature and pressure increase along the coexistence curve, the gas becomes more like a liquid and the liquid becomes more like a gas. At the critical point, the two are the same. So for temperatures above the critical temperature (126.2 K), there is no phase transition; as pressure increases the gas gradually transforms into something ...

  7. Clausius–Clapeyron relation - Wikipedia

    en.wikipedia.org/wiki/Clausius–Clapeyron_relation

    The Clausius–Clapeyron relation, in chemical thermodynamics, specifies the temperature dependence of pressure, most importantly vapor pressure, at a discontinuous phase transition between two phases of matter of a single constituent. It is named after Rudolf Clausius [1] and Benoît Paul Émile Clapeyron. [2]

  8. Reduced properties - Wikipedia

    en.wikipedia.org/wiki/Reduced_properties

    The reduced temperature of a fluid is its actual temperature, divided by its critical temperature: [1] = where the actual temperature and critical temperature are expressed in absolute temperature scales (either Kelvin or Rankine). Both the reduced temperature and the reduced pressure are often used in thermodynamical formulas like the Peng ...

  9. Temperature–entropy diagram - Wikipedia

    en.wikipedia.org/wiki/Temperature–entropy_diagram

    In thermodynamics, a temperature–entropy (T–s) diagram is a thermodynamic diagram used to visualize changes to temperature (T ) and specific entropy (s) during a thermodynamic process or cycle as the graph of a curve. It is a useful and common tool, particularly because it helps to visualize the heat transfer during a process.