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For example, if an electron wave packet is initially localized in a region of atomic dimensions (i.e., 10 −10 m) then the width of the packet doubles in about 10 −16 s. Clearly, particle wave packets spread out very rapidly indeed (in free space): [17] For instance, after 1 ms, the width will have grown to about a kilometer.
The definition of the Gibbs function is = + where H is the enthalpy defined by: = +. Taking differentials of each definition to find dH and dG, then using the fundamental thermodynamic relation (always true for reversible or irreversible processes): = where S is the entropy, V is volume, (minus sign due to reversibility, in which dU = 0: work other than pressure-volume may be done and is equal ...
Here ψ is the angle between the path of the wave source and the direction of wave propagation (the wave vector k), and the circles represent wavefronts. Consider one of the phase circles of Fig.12.3 for a particular k , corresponding to the time t in the past, Fig.12.2.
The function s(x, t) is often called the source function because in practice it describes the effects of the sources of waves on the medium carrying them. Physical examples of source functions include the force driving a wave on a string, or the charge or current density in the Lorenz gauge of electromagnetism.
Each has an energy related to the frequency of the wave given by Planck's relation E = hf, where E is the energy of the photon, h is the Planck constant, 6.626 × 10 −34 J·s, and f is the frequency of the wave. [40] In a medium (other than vacuum), velocity factor or refractive index are considered, depending on frequency and application ...
For example, a wavenumber in inverse centimeters can be converted to a frequency expressed in the unit gigahertz by multiplying by 29.979 2458 cm/ns (the speed of light, in centimeters per nanosecond); [5] conversely, an electromagnetic wave at 29.9792458 GHz has a wavelength of 1 cm in free space. In theoretical physics, a wave number, defined ...
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