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In 1890, Rydberg proposed on a formula describing the relation between the wavelengths in spectral lines of alkali metals. [2]: v1:376 He noticed that lines came in series and he found that he could simplify his calculations using the wavenumber (the number of waves occupying the unit length, equal to 1/λ, the inverse of the wavelength) as his unit of measurement.
Wavenumber, as used in spectroscopy and most chemistry fields, is defined as the number of wavelengths per unit distance, typically centimeters (cm −1): ~ =, where λ is the wavelength. It is sometimes called the "spectroscopic wavenumber". [1]
Woodward's rules, named after Robert Burns Woodward and also known as Woodward–Fieser rules (for Louis Fieser) are several sets of empirically derived rules which attempt to predict the wavelength of the absorption maximum (λ max) in an ultraviolet–visible spectrum of a given compound.
The last expression in the first equation shows that the wavelength of light needed to ionize a hydrogen atom is 4π/α times the Bohr radius of the atom. The second equation is relevant because its value is the coefficient for the energy of the atomic orbitals of a hydrogen atom: = /.
Balmer noticed that a single wavelength had a relation to every line in the hydrogen spectrum that was in the visible light region. That wavelength was 364.506 82 nm . When any integer higher than 2 was squared and then divided by itself squared minus 4, then that number multiplied by 364.506 82 nm (see equation below) gave the wavelength of ...
The wavelength of a sine wave, λ, can be measured between any two points with the same phase, such as between crests (on top), or troughs (on bottom), or corresponding zero crossings as shown. In physics and mathematics, wavelength or spatial period of a wave or periodic function is the distance over which the wave's shape repeats.
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
Planck–Einstein equation and de Broglie wavelength relations P = (E/c, p) ... Defining equation (physical chemistry) List of electromagnetism equations;