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For most non-electrolytes dissolved in water, the van 't Hoff factor is essentially 1. For most ionic compounds dissolved in water, the van 't Hoff factor is equal to the number of discrete ions in a formula unit of the substance. This is true for ideal solutions only, as occasionally ion pairing occurs in solution. At a given instant a small ...
Jacobus van 't Hoff found a quantitative relationship between osmotic pressure and solute concentration, expressed in the following equation: Π = i c R T {\displaystyle \Pi =icRT} where Π {\displaystyle \Pi } is osmotic pressure, i is the dimensionless van 't Hoff index , c is the molar concentration of solute, R is the ideal gas constant ...
Osmolality of blood increases with dehydration and decreases with overhydration. In normal people, increased osmolality in the blood will stimulate secretion of antidiuretic hormone (ADH). This will result in increased water reabsorption, more concentrated urine, and less concentrated blood plasma. A low serum osmolality will suppress the ...
For example, the intracellular fluid and extracellular can be hyperosmotic, but isotonic – if the total concentration of solutes in one compartment is different from that of the other, but one of the ions can cross the membrane (in other words, a penetrating solute), drawing water with it, thus causing no net change in solution volume.
i is the van ‘t Hoff factor, the number of particles the solute splits into or forms when dissolved; b is the molality of the solution. Through cryoscopy, a known constant can be used to calculate an unknown molar mass. The term "cryoscopy" means "freezing measurement" in Greek.
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".
i is the van 't Hoff factor, the number of particles the solute splits into or forms when dissolved. b is the molality of the solution. A formula to compute the ebullioscopic constant is: [2] = R is the ideal gas constant. M is the molar mass of the solvent.
where is the chemical potential of the pure solvent and is the chemical potential of the solvent in a solution, M A is its molar mass, x A its mole fraction, R the gas constant and T the temperature in Kelvin. [1] The latter osmotic coefficient is sometimes called the rational osmotic coefficient. The values for the two definitions are ...