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Interstitial atoms (blue) occupy some of the spaces within a lattice of larger atoms (red) In materials science, an interstitial defect is a type of point crystallographic defect where an atom of the same or of a different type, occupies an interstitial site in the crystal structure.
In crystallography, interstitial sites, holes or voids are the empty space that exists between the packing of atoms (spheres) in the crystal structure. [ citation needed ] The holes are easy to see if you try to pack circles together; no matter how close you get them or how you arrange them, you will have empty space in between.
Larger defects in an ordered structure are usually considered dislocation loops. For historical reasons, many point defects, especially in ionic crystals, are called centers: for example a vacancy in many ionic solids is called a luminescence center, a color center, or F-center. These dislocations permit ionic transport through crystals leading ...
Assume the chemical composition is AX, with A being the cation and X being the anion. (The following assumes that X is a diatomic gas such as oxygen and therefore cation A has a +2 charge. Note that materials with this defect structure are often used in oxygen sensors.) In the reduced n-type, there are excess cations on the interstitial sites: A ×
Dans une structure cubique à faces centrées, un site interstitiel octaédrique est mis en évidence en rouge, et un site tétraédrique est mis en évidence en bleu. In a face centered cubic structure, an octahedral interstitial site is highlighted in red, and a tetrahedral interstitial site is highlighted in blue.
Interstitial sites refer to the empty spaces in between the atoms in the crystal lattice. These spaces can be filled by oppositely charged ions to form multi-element structures. They can also be filled by impurity atoms or self-interstitials to form interstitial defects.
In crystallography, a Frenkel defect is a type of point defect in crystalline solids, named after its discoverer Yakov Frenkel. [1] The defect forms when an atom or smaller ion (usually cation) leaves its place in the structure, creating a vacancy and becomes an interstitial by lodging in a nearby location. [2]
The defects affect the material properties of diamond and determine to which type a diamond is assigned; the most dramatic effects are on the diamond color and electrical conductivity, as explained by the electronic band structure. The defects can be detected by different types of spectroscopy, including electron paramagnetic resonance (EPR ...