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Alcohol by volume (abbreviated as alc/vol or ABV) is a standard measure of the volume of alcohol contained in a given volume of an alcoholic beverage, expressed as a volume percent. [ 1 ] [ 2 ] [ 3 ] It is defined as the number of millilitres (mL) of pure ethanol present in 100 mL (3.5 imp fl oz; 3.4 US fl oz) of solution at 20 °C (68 °F).
To create the solution, 11.6 g NaCl is placed in a volumetric flask, dissolved in some water, then followed by the addition of more water until the total volume reaches 100 mL. The density of water is approximately 1000 g/L and its molar mass is 18.02 g/mol (or 1/18.02 = 0.055 mol/g). Therefore, the molar concentration of water is
It was exactly equal before the redefinition of the mole in 2019, and is now only approximately equal, but the difference is negligible for all practical purposes. Thus, for example, the average mass of a molecule of water is about 18.0153 daltons, and the molar mass of water is about 18.0153 g/mol.
The concentration of alcohol in a beverage is usually stated as the percentage of alcohol by volume (ABV, the number of milliliters (ml) of pure ethanol in 100 ml of beverage) or as proof. In the United States, proof is twice the percentage of alcohol by volume at 60 degrees Fahrenheit (e.g. 80 proof = 40% ABV).
The theoretical molar yield is 2.0 mol (the molar amount of the limiting compound, acetic acid). The molar yield of the product is calculated from its weight (132 g ÷ 88 g/mol = 1.5 mol). The % yield is calculated from the actual molar yield and the theoretical molar yield (1.5 mol ÷ 2.0 mol × 100% = 75%). [citation needed]
Thus pure 100% alcohol will have 100×(7 ⁄ 4) = 175 proof, and a spirit containing 40% ABV will have 40×(7 ⁄ 4) = 70 proof. The proof system in the United States was established around 1848 and was based on percent alcohol rather than specific gravity. Fifty percent alcohol by volume was defined as 100 proof. [4]
Here is a similar formula from the 67th edition of the CRC handbook. Note that the form of this formula as given is a fit to the Clausius–Clapeyron equation, which is a good theoretical starting point for calculating saturation vapor pressures:
Molar mass: 134.178 g·mol −1 Density: 1.0397 g/cm 3 at 35 °C ... Cinnamyl alcohol or styron [2] is an organic compound that is found in esterified form in storax, ...