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More rapid diffusion along grain boundaries than along grain interiors; Faster nucleation and growth of precipitates at the grain boundaries; Quench cracking, or crack growth following a quenching process, is another example of intergranular fracture and almost always occurs by intergranular processes. [6]
In materials science, a grain boundary is the interface between two grains, or crystallites, in a polycrystalline material. Grain boundaries are two-dimensional defects in the crystal structure , and tend to decrease the electrical and thermal conductivity of the material.
The fracture behavior of materials can be significantly changed by the use of precipitation-based grain boundary design. For example, Meindlhumer et. al. [9] produced a thin film of AlCrN containing a specific distribution of precipitates within the grain boundaries in precipitation-based grain boundary design. The precipitates acted as a ...
In metallurgy, materials science and structural geology, subgrain rotation recrystallization is recognized as an important mechanism for dynamic recrystallisation.It involves the rotation of initially low-angle sub-grain boundaries until the mismatch between the crystal lattices across the boundary is sufficient for them to be regarded as grain boundaries.
There are mainly two types of grain boundary sliding: Rachinger sliding, [2] and Lifshitz sliding. [3] Grain boundary sliding usually occurs as a combination of both types of sliding. Boundary shape often determines the rate and extent of grain boundary sliding. [4] Grain boundary sliding is a motion to prevent intergranular cracks from forming.
Grain boundary engineering involves manipulating the grain boundary structure and energy to enhance mechanical properties. By controlling the interfacial energy, it is possible to engineer materials with desirable grain boundary characteristics, such as increased interfacial area, higher grain boundary density, or specific grain boundary types ...
Treating a grain boundary geometrically as an interface of a single crystal cut into two parts, one of which is rotated, we see that there are five variables required to define a grain boundary. The first two numbers come from the unit vector that specifies a rotation axis. The third number designates the angle of rotation of the grain.
A model of grain boundary diffusion developed by JC Fisher in 1953. This solution can then be modeled via a modified differential solution to Fick's Second Law that adds a term for sideflow out of the boundary, given by the equation + (,) = ′, where ′ is the diffusion coefficient, is the boundary width, and (,) is the rate of sideflow.