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Hypophosphorous acid was first prepared in 1816 by the French chemist Pierre Louis Dulong (1785–1838). [4]The acid is prepared industrially via a two step process: Firstly, elemental white phosphorus reacts with alkali and alkaline earth hydroxides to give an aqueous solution of hypophosphites:
Note: in dilute aqueous solution the formation of the hydronium ion, H 3 O + (aq), is effectively complete, so that hydration of the proton can be ignored in relation to the equilibria. Other examples of inorganic polyprotic acids include anions of sulfuric acid , phosphoric acid and hydrogen sulfide that have lost one or more protons.
The general formula of a phosphoric acid is H n−2x+2 P n O 3n−x+1, where n is the number of phosphorus atoms and x is the number of fundamental cycles in the molecule's structure; that is, the minimum number of bonds that would have to be broken to eliminate all cycles.
Trisodium phosphate (TSP) is an inorganic compound with the chemical formula Na 3 P O 4. It is a white, granular or crystalline solid, highly soluble in water, producing an alkaline solution. TSP is used as a cleaning agent, builder, lubricant, food additive, stain remover, and degreaser. [7]
Ammonium phosphomolybdate is the inorganic salt of phosphomolybdic acid with the chemical formula (NH 4) 3 PMo 12 O 40. The salt contains the phosphomolybdate anion, a well known heteropolymetalate of the Keggin structural class.
Disodium phosphate (DSP), or disodium hydrogen phosphate, or sodium phosphate dibasic, is an inorganic compound with the chemical formula Na 2 H P O 4. It is one of several sodium phosphates . The salt is known in anhydrous form as well as hydrates Na 2 HPO 4 · n H 2 O , where n is 2, 7, 8, and 12.
It reduces solutions of noble metal cations to the metals. When phosphorous acid is treated with a cold solution of mercuric chloride, a white precipitate of mercurous chloride forms: H 3 PO 3 + 2 HgCl 2 + H 2 O → Hg 2 Cl 2 + H 3 PO 4 + 2 HCl. Mercurous chloride is reduced further by phosphorous acid to mercury on heating or on standing:
The sodium fusion extract is made alkaline by adding NaOH. To this mixture, freshly prepared FeSO 4 solution is added and boiled for some time and then cooled. A few drops of FeCl 3 are added and Prussian blue (bluish green) color forms due to formation of ferric ferrocyanide along with NaCl. This shows the presence of nitrogen in the organic ...