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The Corey–House synthesis (also called the Corey–Posner–Whitesides–House reaction and other permutations) is an organic reaction that involves the reaction of a lithium diorganylcuprate with an organic halide or pseudohalide (′) to form a new alkane, as well as an ill-defined organocopper species and lithium (pseudo)halide as byproducts.
In organic chemistry, peptide synthesis is the production of peptides, compounds where multiple amino acids are linked via amide bonds, also known as peptide bonds. Peptides are chemically synthesized by the condensation reaction of the carboxyl group of one amino acid to the amino group of another.
Molecular models of the different molecules active in Piranha solution: peroxysulfuric acid (H 2 SO 5) and hydrogen peroxide (H 2 O 2). Piranha solution, also known as piranha etch, is a mixture of sulfuric acid (H 2 SO 4) and hydrogen peroxide (H 2 O 2). The resulting mixture is used to clean organic residues off substrates, for example ...
A full edition was published in 1979, [1] an abridged and updated version of which was published in 1993 as A Guide to IUPAC Nomenclature of Organic Compounds. [2] Both of these are now out-of-print in their paper versions, but are available free of charge in electronic versions.
Contributing structures of the carbonate ion. In chemistry, resonance, also called mesomerism, is a way of describing bonding in certain molecules or polyatomic ions by the combination of several contributing structures (or forms, [1] also variously known as resonance structures or canonical structures) into a resonance hybrid (or hybrid structure) in valence bond theory.
Due to the presence of solvated electrons, these solutions are very powerful reducing agents used in organic synthesis. Reduction reactions using sodium in liquid ammonia. Reaction 1) is known as Birch reduction. Other reductions [143] that can be carried by these solutions are: S 8 + 2e − → S 8 2-Fe(CO) 5 + 2e − → Fe(CO) 4 2-+ CO
Hydrogen cyanide is a linear molecule, with a triple bond between carbon and nitrogen.The tautomer of HCN is HNC, hydrogen isocyanide. [citation needed]HCN has a faint bitter almond-like odor that some people are unable to detect owing to a recessive genetic trait. [12]
Methanol and its vapours are flammable. Moderately toxic for small animals – Highly toxic to large animals and humans (in high concentrations) – May be fatal/lethal or cause blindness and damage to the liver, kidneys, and heart if swallowed – Toxicity effects from repeated over exposure have an accumulative effect on the central nervous system, especially the optic nerve – Symptoms may ...