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Copper(II) chloride, also known as cupric chloride, is an inorganic compound with the chemical formula Cu Cl 2. The monoclinic yellowish-brown anhydrous form slowly absorbs moisture to form the orthorhombic blue-green dihydrate CuCl 2 ·2H 2 O , with two water molecules of hydration .
The main use of copper(I) chloride is as a precursor to the fungicide copper oxychloride. For this purpose aqueous copper(I) chloride is generated by comproportionation and then air-oxidized: [12] Cu + CuCl 2 → 2 CuCl 4 CuCl + O 2 + 2 H 2 O → Cu 3 Cl 2 (OH) 4 + CuCl 2. Copper(I) chloride catalyzes a variety of organic reactions, as
In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystalline material. [1] Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter.
Unit cell definition using parallelepiped with lengths a, b, c and angles between the sides given by α, β, γ [1]. A lattice constant or lattice parameter is one of the physical dimensions and angles that determine the geometry of the unit cells in a crystal lattice, and is proportional to the distance between atoms in the crystal.
In chemistry, crystallography, and materials science, the coordination number, also called ligancy, of a central atom in a molecule or crystal is the number of atoms, molecules or ions bonded to it. The ion/molecule/atom surrounding the central ion/molecule/atom is called a ligand. This number is determined somewhat differently for molecules ...
(c) Demonstration of how quadrupole-quadrupole interactions are involved in the crystal lattice structure. A quadrupole, like a dipole, is a permanent pole but the electric field of the molecule is not linear as in acetone, but in two dimensions. [25] Examples of molecular solids with quadrupoles are octafluoronaphthalene and naphthalene.
The structure thus resembles in some sense the main polymorphs of SiO 2, but cuprous oxide's lattices interpenetrate. Cu 2 O crystallizes in a cubic structure with a lattice constant a l = 4.2696 Å. The copper atoms arrange in a fcc sublattice, the oxygen atoms in a bcc sublattice. One sublattice is shifted by a quarter of the body diagonal.
Host–guest chemistry encompasses the idea of molecular recognition and interactions through non-covalent bonding. Non-covalent bonding is critical in maintaining the 3D structure of large molecules, such as proteins and is involved in many biological processes in which large molecules bind specifically but transiently to one another.
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