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Crystal growth is achieved by the further addition of folded polymer chain segments and only occurs for temperatures below the melting temperature T m and above the glass transition temperature T g. Higher temperatures destroy the molecular arrangement and below the glass transition temperature, the movement of molecular chains is frozen. [6]
Perfectly isotactic PP has a melting point of 171 °C (340 °F). Commercial isotactic PP has a melting point that ranges from 160 to 166 °C (320 to 331 °F), depending on atactic material and crystallinity. Syndiotactic PP with a crystallinity of 30% has a melting point of 130 °C (266 °F). [8] Below 0 °C, PP becomes brittle. [9]
Compared to amorphous structures, semi-crystalline structures lead to a higher stiffness, density, melting temperature and higher resistance of a polymer. Cross-linked polymers: Wide-meshed cross-linked polymers are elastomers and cannot be molten (unlike thermoplastics); heating cross-linked polymers only leads to decomposition.
PTFE is a thermoplastic polymer, which is a white solid at room temperature, with a density of about 2200 kg/m 3 and a melting point of 600 K (327 °C; 620 °F). [27] It maintains high strength, toughness and self-lubrication at low temperatures down to 5 K (−268.2 °C; −450.7 °F), and good flexibility at temperatures above 194 K (−79.15 ...
The melting point for average commercial low-density polyethylene is typically 105 to 115 °C (221 to 239 °F). These temperatures vary strongly with the type of polyethylene, but the theoretical upper limit of melting of polyethylene is reported to be 144 to 146 °C (291 to 295 °F). Combustion typically occurs above 349 °C (660 °F).
Acrylonitrile butadiene styrene (ABS) (chemical formula (C 8 H 8) x · (C 4 H 6) y · (C 3 H 3 N) z) is a common thermoplastic polymer. Its glass transition temperature is approximately 105 °C (221 °F). [4] ABS is amorphous and therefore has no true melting point. ABS is a terpolymer made by polymerizing styrene and acrylonitrile in the ...
The glass transition temperature of Nylon 6 is 47 °C. As a synthetic fibre, Nylon 6 is generally white but can be dyed in a solution bath prior to production for different color results. Its tenacity is 6–8.5 gf/D with a density of 1.14 g/cm 3. Its melting point is at 215 °C and can protect heat up to 150 °C on average. [4]
The presence of chloride groups gives the polymer very different properties from the structurally related material polyethylene. [17] At 1.4 g/cm 3, PVC's density is also higher than structurally related plastics such as polyethylene (0.88–0.96 g/cm 3) and polymethylmethacrylate (1.18 g/cm 3).