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In thermodynamics, a critical point (or critical state) is the end point of a phase equilibrium curve. One example is the liquid–vapor critical point, the end point of the pressure–temperature curve that designates conditions under which a liquid and its vapor can coexist.
Attributes of the resulting crystal depend largely on factors such as temperature, air pressure, cooling rate, and in the case of liquid crystals, time of fluid evaporation. Crystallization occurs in two major steps. The first is nucleation, the appearance of a crystalline phase from either a supercooled liquid or a supersaturated solvent.
The phenomenon is most commonly demonstrated in binary fluid mixtures, such as methanol and cyclohexane.As the critical point is approached, the sizes of the gas and liquid region begin to fluctuate over increasingly large length scales (the correlation length of the liquid diverges).
The first report of the hydrothermal growth of crystals [4] was by German geologist Karl Emil von Schafhäutl (1803–1890) in 1845: he grew microscopic quartz crystals in a pressure cooker. [5] In 1848, Robert Bunsen reported growing crystals of barium and strontium carbonate at 200 °C and at pressures of 15 atmospheres, using sealed glass ...
Crystallization: This is the initial phase where the material to be purified is cooled. As it cools, high-purity crystals begin to form on the cooling surface. The purity is achieved because the impurities tend to remain in the liquid phase rather than being incorporated into the crystal structure.
A science project is an educational activity for students involving experiments or construction of models in one of the science disciplines. Students may present their science project at a science fair, so they may also call it a science fair project. Science projects may be classified into four main types.
In addition, physical properties are often controlled by crystalline defects. The understanding of crystal structures is an important prerequisite for understanding crystallographic defects. Most materials do not occur as a single crystal, but are poly-crystalline in nature (they exist as an aggregate of small crystals with different orientations).
The term 'crystal engineering' was first used in 1955 by R. Pepinsky [4] but the starting point is often credited to Gerhard Schmidt [5] in connection with photodimerization reactions in crystalline cinnamic acids. Since this initial use, the meaning of the term has broadened considerably to include many aspects of solid state supramolecular ...