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Ammonium thiocyanate is used in the manufacture of herbicides, thiourea, and transparent artificial resins; in matches; as a stabilizing agent in photography; in various rustproofing compositions; as an adjuvant in textile dyeing and printing; as a tracer in oil fields; in the separation of hafnium from zirconium (important for the production of hafnium-free zircalloy for use in nuclear fuel ...
[7] [8] [9] Thus the complete absence of thiocyanate or reduced thiocyanate [10] in the human body, (e.g., cystic fibrosis) is damaging to the human host defense system. [11] [12] Thiocyanate is a potent competitive inhibitor of the thyroid sodium-iodide symporter. [13] Iodine is an essential component of thyroxine. Since thiocyanates will ...
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".
For example, tetramethylammonium thiocyanate may be prepared from ammonium thiocyanate as follows: [7] NMe 4 + OH − + NH 4 + SCN − → NMe 4 + SCN − + NH 3 + H 2 O. TMAH and many other TMA salts containing simple anions thermally decompose into trimethylamine. [8] Dimethyl ether is a major decomposition product rather than methanol. [9 ...
Addition of a thiocyanate salt to a solution containing ferric ions gives a deep red color. The identity of the chromophore remains unknown. [15] The reverse was also used: testing for the presence of thiocyanate by the addition of ferric salts. The 1:1 complex of thiocyanate and iron is deeply red. The effect was first reported in 1826. [16]
In methyl thiocyanate, N≡C and C−S distances are 116 and 176 pm. By contrast, N=C and C=S distances are 117 and 158 pm in isothiocyanates. [7] Typical bond angles for C−S−C are 100°. [3] By contrast C−N=C in aryl isothiocyanates is 165°. Again, the thiocyanate isomers are quite different with C−S−C angle near 100°.
Thiourea (/ ˌ θ aɪ. oʊ j ʊəˈr iː. ə,-ˈ jʊər i-/) [2] [3]}} is an organosulfur compound with the formula SC(NH 2) 2 and the structure H 2 N−C(=S)−NH 2.It is structurally similar to urea (H 2 N−C(=O)−NH 2), with the oxygen atom replaced by sulfur atom (as implied by the thio-prefix).
A frigorific mixture is a mixture of two or more phases in a chemical system that, so long as none of the phases are completely consumed during equilibration, reaches an equilibrium temperature that is independent of the starting temperature of the phases before they are mixed. The equilibrium temperature is also independent of the quantities ...