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Ammonium thiocyanate is used in the manufacture of herbicides, thiourea, and transparent artificial resins; in matches; as a stabilizing agent in photography; in various rustproofing compositions; as an adjuvant in textile dyeing and printing; as a tracer in oil fields; in the separation of hafnium from zirconium (important for the production of hafnium-free zircalloy for use in nuclear fuel ...
The concept of chemical equilibrium was developed in 1803, after Berthollet found that some chemical reactions are reversible. [4] For any reaction mixture to exist at equilibrium, the rates of the forward and backward (reverse) reactions must be equal. In the following chemical equation, arrows point both ways to indicate equilibrium. [5]
Thiocyanate [6] is known to be an important part in the biosynthesis of hypothiocyanite by a lactoperoxidase. [7] [8] [9] Thus the complete absence of thiocyanate or reduced thiocyanate [10] in the human body, (e.g., cystic fibrosis) is damaging to the human host defense system.
Thiourea (/ ˌ θ aɪ. oʊ j ʊəˈr iː. ə,-ˈ jʊər i-/) [2] [3]}} is an organosulfur compound with the formula SC(NH 2) 2 and the structure H 2 N−C(=S)−NH 2.It is structurally similar to urea (H 2 N−C(=O)−NH 2), with the oxygen atom replaced by sulfur atom (as implied by the thio-prefix).
The equation of chemical equilibrium can be expressed symbolically as reactant(s) ⇌ product(s) The sign ⇌ means "are in equilibrium with". This definition refers to macroscopic properties. Changes do occur at the microscopic level of atoms and molecules, but to such a minute extent that they are not measurable and in a balanced way so that ...
For example, tetramethylammonium thiocyanate may be prepared from ammonium thiocyanate as follows: [7] NMe 4 + OH − + NH 4 + SCN − → NMe 4 + SCN − + NH 3 + H 2 O. TMAH and many other TMA salts containing simple anions thermally decompose into trimethylamine. [8] Dimethyl ether is a major decomposition product rather than methanol. [9 ...
In methyl thiocyanate, N≡C and C−S distances are 116 and 176 pm. By contrast, N=C and C=S distances are 117 and 158 pm in isothiocyanates. [7] Typical bond angles for C−S−C are 100°. [3] By contrast C−N=C in aryl isothiocyanates is 165°. Again, the thiocyanate isomers are quite different with C−S−C angle near 100°.
Any salt containing the ion, such as ammonium cyanate, is called a cyanate. The cyanate ion is an isomer of the much-less-stable fulminate anion, CNO − or [C − ≡N + −O −]. [1] The cyanate ion is an ambidentate ligand, forming complexes with a metal ion in which either the nitrogen or oxygen atom may be the electron-pair donor.