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It is usually applied to gases: a monatomic gas is a gas in which atoms are not bound to each other. Examples at standard conditions of temperature and pressure include all the noble gases ( helium , neon , argon , krypton , xenon , and radon ), though all chemical elements will be monatomic in the gas phase at sufficiently high temperature (or ...
Based on atomicity, molecules can be classified as: Monoatomic (composed of one atom). Examples include He , Ne , Ar , and Kr . All noble gases are monoatomic. Diatomic (composed of two atoms). Examples include H 2 , N 2 , O 2 , F 2 , and Cl 2 .
By the equipartition theorem, internal energy per mole of gas equals c v T, where T is absolute temperature and the specific heat at constant volume is c v = (f)(R/2). R = 8.314 J/(K mol) is the universal gas constant, and "f" is the number of thermodynamic (quadratic) degrees of freedom, counting the number of ways in which energy can occur.
Helium is the least water-soluble monatomic gas, [96] and one of the least water-soluble of any gas (CF 4, SF 6, and C 4 F 8 have lower mole fraction solubilities: 0.3802, 0.4394, and 0.2372 x 2 /10 −5, respectively, versus helium's 0.70797 x 2 /10 −5), [97] and helium's index of refraction is closer to unity than that of any other gas. [98]
Hence, all the energy possessed by the gas is the kinetic energy of the molecules, or atoms, of the gas. = This corresponds to the kinetic energy of n moles of a monoatomic gas having 3 degrees of freedom; x, y, z. The table here below gives this relationship for different amounts of a monoatomic gas.
Ions consisting of only a single atom are termed atomic or monatomic ions, while two or more atoms form molecular ions or polyatomic ions. In the case of physical ionization in a fluid (gas or liquid), "ion pairs" are created by spontaneous molecule collisions, where each generated pair consists of a free electron and a positive ion. [ 5 ]
ĉ V is the dimensionless specific heat capacity at constant volume, approximately 3 / 2 for a monatomic gas, 5 / 2 for diatomic gas, and 3 for non-linear molecules if we treat translations and rotations classically and ignore quantum vibrational contribution and electronic excitation.
[13] [14] The constituents of molecular solids range in size from condensed monatomic gases [15] to small molecules (i.e. naphthalene and water) [16] [17] to large molecules with tens of atoms (i.e. fullerene with 60 carbon atoms). [18]