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In chemistry, Le Chatelier's principle (pronounced UK: / l ə ʃ æ ˈ t ɛ l j eɪ / or US: / ˈ ʃ ɑː t əl j eɪ /) [1] is a principle used to predict the effect of a change in conditions on chemical equilibrium. [2] Other names include Chatelier's principle, Braun–Le Chatelier principle, Le Chatelier–Braun principle or the equilibrium ...
Henry Louis Le Chatelier [1] (French pronunciation: [ɑ̃ʁi lwi lə ʃɑtəlje]; 8 October 1850 – 17 September 1936) was a French chemist of the late 19th and early 20th centuries. He devised Le Chatelier's principle, used by chemists and chemical engineers to predict the effect a changing condition has on a system in chemical equilibrium.
According to Le Chatelier's principle, the addition of acetate ions from sodium acetate will suppress the ionization of acetic acid and shift its equilibrium to the left. Thus the percent dissociation of the acetic acid will decrease, and the pH of the solution will increase.
The generalized Le Chatelier principle is for a maximum condition of equilibrium: where all unknowns of the function are independently variable, auxiliary constraints ("just-binding" in leaving initial equilibrium unchanged) reduce the response to a parameter change.
Le Châtelier's principle (1884) predicts the behavior of an equilibrium system when changes to its reaction conditions occur. If a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium moves to partially reverse the change. For example, adding more S (to the chemical reaction above) from the outside will ...
By Le Chatelier's principle, the release of CO 2 from the lungs pushes the reaction above to the left, causing carbonic anhydrase to form CO 2 until all excess protons are removed. Bicarbonate concentration is also further regulated by renal compensation , the process by which the kidneys regulate the concentration of bicarbonate ions by ...
This equation is in accordance with Le Chatelier's principle. K p will remain constant with temperature. The addition of pressure to the system will increase the value of p T, so α must decrease to keep K p constant.
Le Chatelier's principle indicates that the reaction is more favorable to reduction as the concentration of Cu 2+ ions increases. Reduction will take place in the cell's compartment where the concentration is higher and oxidation will occur on the more dilute side.