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The Frasch process is a method to extract sulfur from underground deposits by taking advantage of the low melting point of sulfur. It is the only industrial method of recovering sulfur from elemental deposits. [1] Most of the world's sulfur was obtained this way until the late 20th century, when sulfur recovered from petroleum and gas sources ...
The contact process is a method of producing sulfuric acid in the high concentrations needed for industrial processes. Platinum was originally used as the catalyst for this reaction; however, because it is susceptible to reacting with arsenic impurities in the sulfur feedstock, vanadium(V) oxide (V 2 O 5) has since been preferred.
The vast majority of the 64,000,000 tonnes of sulfur produced worldwide in 2005 was byproduct sulfur from refineries and other hydrocarbon processing plants. [3] [4] [5] Sulfur is used for manufacturing sulfuric acid, medicine, cosmetics, fertilizers and rubber products. Elemental sulfur is used as fertilizer and pesticide.
In its most basic form the ores were piled in a mound and ignited. The semi-pure sulfur flowed down and the solidified mass was collected at a lower level. It was the only industrial method of recovering sulfur from elemental deposits until replaced by the Frasch process. [1] Most of the world's sulfur was obtained this way until the late 19th ...
The wet sulfuric acid process (WSA process) is a gas desulfurization process. After Danish company Haldor Topsoe introduced this technology in 1987, it has been recognized as a process for recovering sulfur from various process gases in the form of commercial quality sulfuric acid (H 2 SO 4) with the simultaneous production of high-pressure steam.
The sulfur is recovered as concentrated sulfuric acid and the nitrogen oxides are reduced to free nitrogen. The process is based on the well-known wet sulfuric acid process (WSA), a process for recovering sulfur from various process gasses in the form of commercial quality sulfuric acid (H 2 SO 4 ).
Desulfurization or desulphurisation is a chemical process for the removal of sulfur from a material. [1] The term usually refers to the removal of sulfur from a molecule or a material by hydrogenolysis: [2] R 2 S + 2 H 2 → 2RH + H 2 S. Hydrogen is the ultimate sulfur acceptor. As applied to oil refinery streams, the conversion is known as ...
To minimize the problem, the combustion is often conducted in the presence of calcium oxide or calcium carbonate, which, directly or indirectly, bind sulfur dioxide and some oxygen to give calcium sulfite. [1] The net reaction is: CaO + SO 2 → CaSO 3 2 CaSO 3 + O 2 → 2 CaSO 4. or the net reaction is sulfation, the addition of SO 3: CaO + SO ...