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In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in which electrons are normally present at absolute zero temperature, while the conduction band is the lowest range of vacant electronic states.
The name "valence band" was coined by analogy to chemistry, since in semiconductors (and insulators) the valence band is built out of the valence orbitals. In a metal or semimetal, the Fermi level is inside of one or more allowed bands. In semimetals the bands are usually referred to as "conduction band" or "valence band" depending on whether ...
The valence shell is the set of orbitals which are energetically accessible for accepting electrons to form chemical bonds. For main-group elements, the valence shell consists of the ns and np orbitals in the outermost electron shell.
There are two recognized types of charge carriers in semiconductors.One is electrons, which carry a negative electric charge.In addition, it is convenient to treat the traveling vacancies in the valence band electron population as a second type of charge carrier, which carry a positive charge equal in magnitude to that of an electron.
Radicals are uncommon in s- and p-block chemistry, since the unpaired electron occupies a valence p orbital or an sp, sp 2 or sp 3 hybrid orbital. These orbitals are strongly directional and therefore overlap to form strong covalent bonds, favouring dimerisation of radicals.
A quasi Fermi level is a term used in quantum mechanics and especially in solid state physics for the Fermi level (chemical potential of electrons) that describes the population of electrons separately in the conduction band and valence band, when their populations are displaced from equilibrium.
In a semimetal, the bottom of the conduction band is typically situated in a different part of momentum space (at a different k-vector) than the top of the valence band. One could say that a semimetal is a semiconductor with a negative indirect bandgap , although they are seldom described in those terms.
The intense blue color of Prussian blue is a consequence of an intervalence charge transfer band. In chemistry, intervalence charge transfer, often abbreviated IVCT or even IT, is a type of charge-transfer band that is associated with mixed valence compounds. It is most common for systems with two metal sites differing only in oxidation state.