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As potassium permanganate is titrated, the solution becomes a light shade of purple, which darkens as excess of the titrant is added to the solution. In a related way, it is used as a reagent to determine the Kappa number of wood pulp. For the standardization of KMnO 4 solutions, reduction by oxalic acid is often used. [47]
Oxalic acid is an organic acid with the systematic name ethanedioic acid and chemical formula HO−C(=O)−C(=O)−OH, also written as (COOH) 2 or (CO 2 H) 2 or H 2 C 2 O 4. It is the simplest dicarboxylic acid. It is a white crystalline solid that forms a colorless solution in water.
A permanganate can oxidize an amine to a nitro compound, [7] [8] a secondary alcohol to a ketone, [9] a primary alcohol or aldehyde to a carboxylic acid, [10] [11] a terminal alkene to a carboxylic acid, [12] oxalic acid to carbon dioxide, [13] and an alkene to a diol. [14] This list is not exhaustive. In alkene oxidations one intermediate is a ...
It is the sodium salt of oxalic acid. It contains sodium cations Na + and oxalate anions C 2 O 2− 4. It is a white, crystalline, odorless solid, that decomposes above 290 °C. [2] Sodium oxalate can act as a reducing agent, and it may be used as a primary standard for standardizing potassium permanganate (KMnO 4) solutions.
The product was originally sold to bars in Indianapolis and Hoffman asserted in a patent application that the name had been used since January, 1887. [6] [7] The formula contains oxalic acid as a primary ingredient. [8] [9] The Bar Keepers Friend logo represents the swinging doors of a saloon. [10]
Potassium hydrogenoxalate is a salt with formula KHC 2 O 4 or K + ·HO 2 C-CO 2 −.It is one of the most common salts of the hydrogenoxalate anion, and can be obtained by reacting potassium hydroxide with oxalic acid in 1:1 mole ratio.
Oxalate (systematic IUPAC name: ethanedioate) is an anion with the chemical formula C 2 O 2− 4.This dianion is colorless. It occurs naturally, including in some foods. It forms a variety of salts, for example sodium oxalate (Na 2 C 2 O 4), and several esters such as dimethyl oxalate ((CH 3) 2 C 2 O 4).
Potassium manganate is the inorganic compound with the formula K 2 MnO 4. This green-colored salt is an intermediate in the industrial synthesis of potassium permanganate (KMnO 4), a common chemical. [1] Occasionally, potassium manganate and potassium permanganate are confused, but each compound's properties are distinct.