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Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also collectively called epoxy. [1] The IUPAC name for an epoxide group is an oxirane.
It is primarily used as a curing agent or hardener in epoxy chemistry. This can be on its own or reacted with tall oil fatty acid (TOFA) and its dimer to make an amidoamine. [2] This amidoamine is then used as the curing agent for epoxy resin systems. TEPA is a pentadentate ligand in coordination chemistry.
As a reagent in organic chemistry, DBU is used as a ligand and base. As a base, protonation occurs at the imine nitrogen. [5] Lewis acids also attach to the same nitrogen. [6] These properties recommend DBU for use as a catalyst, for example as a curing agent for epoxy resins and polyurethane.
Dimethylaminoethanol is used as a curing agent for polyurethanes and epoxy resins. It is a precursor to other chemicals, such as the nitrogen mustard 2-dimethylaminoethyl chloride. [3] The acrylate ester, dimethylaminoethyl acrylate is used as a flocculating agent. [4]
A compound containing the epoxide functional group can be called an epoxy, epoxide, oxirane, and ethoxyline. Simple epoxides are often referred to as oxides. Thus, the epoxide of ethylene (C 2 H 4) is ethylene oxide (C 2 H 4 O). Many compounds have trivial names; for instance, ethylene oxide is called "oxirane".
The epoxy cycle of ethylene oxide is an almost regular triangle with bond angles of about 60° and a significant angular strain corresponding to the energy of 105 kJ/mol. [22] [23] For comparison, in alcohols the C–O–H angle is about 110°; in ethers, the C–O–C angle is 120°.
BPA Free Plastic. BPS is used in curing fast-drying epoxy glues and as a corrosion inhibitor.It is also commonly used as a reactant in polymer reactions.. BPS has become increasingly common as a building block in polyethersulfone and some epoxies, following the public awareness that BPA has estrogen-mimicking properties, and widespread-belief that enough of it remains in the products to be ...
The Sharpless epoxidation is viable with a large range of primary and secondary alkenic alcohols. Furthermore, with the exception noted above, a given dialkyl tartrate will preferentially add to the same face independent of the substitution on the alkene.To demonstrate the synthetic utility of the Sharpless epoxidation, the Sharpless group created synthetic intermediates of various natural ...