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Nitrogen trichloride, also known as trichloramine, is the chemical compound with the formula NCl 3.This yellow, oily, and explosive liquid is most commonly encountered as a product of chemical reactions between ammonia-derivatives and chlorine (for example, in swimming pools).
The main use for phosphorus tribromide is for conversion of primary or secondary alcohols to alkyl bromides, [9] as described above.PBr 3 usually gives higher yields than hydrobromic acid, and it avoids problems of carbocation rearrangement- for example even neopentyl bromide can be made from the alcohol in 60% yield.
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Electrolyte monitoring is important in the treatment of anorexia and bulimia. In science, electrolytes are one of the main components of electrochemical cells. [2] In clinical medicine, mentions of electrolytes usually refer metonymically to the ions, and (especially) to their concentrations (in blood, serum, urine, or other fluids). Thus ...
An electrolytic cell has three components: an electrolyte and two electrodes (a cathode and an anode). The electrolyte is usually a solution of water or other solvents in which ions are dissolved. Molten salts such as sodium chloride can also function as electrolytes.
To properly fulfil its functions, a supporting electrolyte must meet the following criteria: It must be completely dissociated in aqueous solution, so it is a strong electrolyte with a good conductivity; It must be sufficiently soluble in order to be able to increase the ionic strength of the solution in the experimental conditions to be explored;
m is the molar conductivity at infinite dilution (or limiting molar conductivity), which can be determined by extrapolation of Λ m as a function of √ c, K is the Kohlrausch coefficient, which depends mainly on the stoichiometry of the specific salt in solution, α is the dissociation degree even for strong concentrated electrolytes,
With one equivalent of alcohol and in the absence of base, the first product is alkoxyphosphorodichloridite: [10] PCl 3 + EtOH → PCl 2 (OEt) + HCl. In the absence of base, however, with excess alcohol, phosphorus trichloride converts to diethylphosphite: [11] [12] PCl 3 + 3 EtOH → (EtO) 2 P(O)H + 2 HCl + EtCl. Secondary amines (R 2 NH) form ...