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Phosphoric acid (orthophosphoric acid, monophosphoric acid or phosphoric(V) acid) is a colorless, odorless phosphorus-containing solid, and inorganic compound with the chemical formula H 3 P O 4. It is commonly encountered as an 85% aqueous solution , which is a colourless, odourless, and non- volatile syrupy liquid.
Since the ends are condensed, its formula has one less H 2 O (water) than tripolyphosphoric acid. The general formula of a phosphoric acid is H n−2x+2 P n O 3n−x+1, where n is the number of phosphorus atoms and x is the number of fundamental cycles in the molecule's structure; that is, the minimum number of bonds that would have to be ...
, is the only species present. At pH 13 or higher, the acid is completely dissociated as the phosphate ion, (PO 4) 3−. This means that salts of the mono- and di-phosphate ions can be selectively crystallised from aqueous solution by setting the pH value to either 4.7 or 9.8. In effect, H 3 PO 4, H 2 (PO 4) − and H(PO 4) 2−
The unusual density curve and lower density of ice than of water is essential for much of the life on earth—if water were most dense at the freezing point, then in winter the cooling at the surface would lead to convective mixing. Once 0 °C are reached, the water body would freeze from the bottom up, and all life in it would be killed. [36]
Trisodium phosphate is produced by neutralization of phosphoric acid using sodium carbonate, which produces disodium hydrogen phosphate. The disodium hydrogen phosphate is reacted with sodium hydroxide to form trisodium phosphate and water. Na 2 CO 3 + H 3 PO 4 → Na 2 HPO 4 + CO 2 + H 2 O Na 2 HPO 4 + NaOH → Na 3 PO 4 + H 2 O
Soft drinks containing phosphoric acid, including Coca-Cola, are sometimes called phosphate sodas or phosphates. Phosphoric acid in soft drinks has the potential to cause dental erosion. [108] Phosphoric acid also has the potential to contribute to the formation of kidney stones, especially in those who have had kidney stones previously. [109]
They are magnesium acid salts of phosphoric acid, with varying amounts of water of crystallization: x = 0, 5, 8, 22. [2] The octahydrate forms upon reaction of stoichiometric quantities of monomagnesium phosphate (tetrahydrate) with magnesium hydroxide. Mg(H 2 PO 4) 2 •4H 2 O + 2 Mg(OH) 2 → Mg 3 (PO 4) 2 •8H 2 O
It is a white or colorless solid that is soluble in water. It is produced commercially by partial neutralization of phosphoric acid with two equivalents of potassium chloride: [1] H 3 PO 4 + 2 KCl → K 2 HPO 4 + 2 HCl