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A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.
A pendulum with a period of 2.8 s and a frequency of 0.36 Hz. For cyclical phenomena such as oscillations, waves, or for examples of simple harmonic motion, the term frequency is defined as the number of cycles or repetitions per unit of time.
Wavenumber, as used in spectroscopy and most chemistry fields, is defined as the number of wavelengths per unit distance, typically centimeters (cm −1): ~ =, where λ is the wavelength. It is sometimes called the "spectroscopic wavenumber". [1] It equals the spatial frequency.
chemical physics A branch of chemistry and physics that studies chemical processes from the point of view of physics by investigating physicochemical phenomena using techniques from atomic and molecular physics and condensed matter physics. chromatic aberration circular motion classical mechanics. Also called Newtonian mechanics.
Chemical shift δ is usually expressed in parts per million (ppm) by frequency, because it is calculated from [5] =, where ν sample is the absolute resonance frequency of the sample, and ν ref is the absolute resonance frequency of a standard reference compound, measured in the same applied magnetic field B 0.
Molecular physics is the study of the physical properties of molecules and molecular dynamics. The field overlaps significantly with physical chemistry , chemical physics , and quantum chemistry . It is often considered as a sub-field of atomic, molecular, and optical physics .
Physical chemistry is the study of macroscopic and microscopic phenomena in chemical systems in terms of the principles, practices, and concepts of physics such as motion, energy, force, time, thermodynamics, quantum chemistry, statistical mechanics, analytical dynamics and chemical equilibria.
Collective matter waves are used to model phenomena in solid state physics; standing matter waves are used in molecular chemistry. Matter wave concepts are widely used in the study of materials where different wavelength and interaction characteristics of electrons, neutrons, and atoms are leveraged for advanced microscopy and diffraction ...