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Sodium ethyl xanthate is a pale yellow powder. Its aqueous solutions are stable at high pH if not heated. It rapidly hydrolyses at pH less than 9 at 25 °C. It is the conjugate base of the ethyl xanthic acid, a strong acid with pK a of 1.6 and pK b estimated as 12.4 for the conjugate base. [6]
Sodium salt of ethyl xanthate (sodium ethylxanthate or sodium O-ethyl dithiocarbonate) Structure of a xanthate ester Cellulose xanthate (orange) A xanthate is a salt or ester of a xanthic acid. The formula of the salt of xanthic acid is [R−O−CS 2] − M + (where R is organyl group and M is usually Na or K). [1] Xanthate also refers to the ...
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This Wikipedia page provides a comprehensive list of boiling and freezing points for various solvents.
An example is sodium ethyl xanthate as a collector in the flotation of galena (lead sulfide) to separate it from sphalerite (zinc sulfide). The polar part of xanthate anion attaches to the ore particles and the non-polar hydrocarbon part forms a hydrophobic layer. The particles are brought to the water surface by air bubbles.
The alkali metal thioxanthates are produced by treating a thiol with a base in the presence of carbon disulfide, as illustrated by the preparation of sodium ethyl thioxanthate:. [1] EtSH + NaOH + CS 2 → EtSCS − 2 Na + + H 2 O. Sodium ethyl thioxanthate is similar structurally to sodium ethyl xanthate.
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Ethyl xanthic acid is an organic compound with the chemical formula CH 3 CH 2 −O−C(=S)−SH. It can be viewed as an O-ethyl ester of dithiocarbonic O,S-acid (the formula of that acid is S=C(OH)(SH)). Ethyl xanthic acid belongs to the category of thioacids, where the prefix thio-means that an oxygen atom in the compound is replaced by a ...