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The Bohr model of the hydrogen atom (Z = 1) or a hydrogen-like ion (Z > 1), where the negatively charged electron confined to an atomic shell encircles a small, positively charged atomic nucleus and where an electron jumps between orbits, is accompanied by an emitted or absorbed amount of electromagnetic energy (hν). [1]
The energy of an electron is determined by its orbit around the atom, The n = 0 orbit, commonly referred to as the ground state, has the lowest energy of all states in the system. In atomic physics and chemistry , an atomic electron transition (also called an atomic transition, quantum jump, or quantum leap) is an electron changing from one ...
An electron which is described as being at the "ground state" has a (negative) energy which is equal to the ionization energy of the atom. The electron will reside in this energy level under normal circumstances, unless the ground state is full, in which case additional electrons will reside in higher energy states.
A quantum jump is the abrupt transition of a quantum system (atom, molecule, atomic nucleus) from one quantum state to another, from one energy level to another. When the system absorbs energy, there is a transition to a higher energy level (); when the system loses energy, there is a transition to a lower energy level.
Photons that reach the atom that have an energy of exactly E 2 − E 1 will be absorbed by the electron in state 1, and that electron will jump to state 2. However, photons that are greater or lower in energy cannot be absorbed by the electron, because the electron can jump only to one of the orbitals, it cannot jump to a state between orbitals.
The Bohr model was a precursor of quantum mechanics and of the electron shell model of atoms. Its key feature was that an electron inside an atom occupies one of the atom's "quantum energy levels". Before the collision, an electron inside the mercury atom occupies its lowest available energy level. After the collision, the electron inside ...
The energy necessary to remove an electron from its shell (taking it to infinity) is called the binding energy. Any quantity of energy absorbed by the electron in excess of this amount is converted to kinetic energy according to the conservation of energy. The atom is said to have undergone the process of ionization. If the electron absorbs a ...
Electron excitation is the transfer of a bound electron to a more energetic, but still bound state. This can be done by photoexcitation (PE), where the electron absorbs a photon and gains all its energy [1] or by collisional excitation (CE), where the electron receives energy from a collision with another, energetic electron. [2]