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Chemical structure of the vinyl functional group. In organic chemistry, a vinyl group (abbr. Vi; [1] IUPAC name: ethenyl group [2]) is a functional group with the formula −CH=CH 2.
Vinyl neodecanoate (trade name VeoVa 10) is a vinylic monomer that is virtually always used in combination with other monomers to create latices or emulsion polymers. [3] The trade name is an acronym of Vinyl ester of Versatic Acid with the number 10 meaning 10 carbons in the molecule. It has a medium to low glass transition temperature of -3 °C.
The vinyl cation is a carbocation with the positive charge on an alkene carbon. Its empirical formula of the parent ion is C 2 H + 3.Vinyl cation are invoked as reactive intermediates in solvolysis of vinyl halides, [1] [2] as well as electrophilic addition to alkynes and allenes.
Delocalization of negative charge in a generic carboxylate anion, derived from an organic carboxylic acid (cf. acetic acid), and the corresponding vinylogous carboxylate anion (the "vinylog/vinylogue" of the carboxylate anion), where a vinyl group now separates the charged oxygen from the carbonyl (C=O) group.
In organic chemistry, vinylation is the process of attaching a vinyl group (CH 2 =CH−) to a substrate.Many organic compounds contain vinyl groups, so the process has attracted significant interest, especially since the reaction scope includes substituted vinyl groups.
The formation of the trans isomer would have indicated that the intermediate carbanion was unstable. [24] Stereochemistry of organolithiums. In the same manner the reaction of (+)-(S)-l-bromo-l-methyl-2,2-diphenylcyclopropane with n-butyllithium followed by quenching with methanol resulted in product with retention of configuration: [25]
In S N 1 case, dissociation is difficult because of the strengthened C-I bond and loss of the iodide will generate an unstable carbocation(see figure 1c) [2] Figure 1. In cross-coupling reactions, typically vinyl iodides react faster and under more mild conditions than vinyl chloride and vinyl bromide. The order of reactivity is based on the ...
Photochromism is the reversible change of color upon exposure to light. It is a transformation of a chemical species (photoswitch) between two forms through the absorption of electromagnetic radiation (photoisomerization), where each form has a different absorption spectra.