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A typical titration curve of a diprotic acid, oxalic acid, titrated with a strong base, sodium hydroxide.Both equivalence points are visible. Titrations are often recorded on graphs called titration curves, which generally contain the volume of the titrant as the independent variable and the pH of the solution as the dependent variable (because it changes depending on the composition of the ...
Inverted logistic S-curve to model the relation between wheat yield and soil salinity. Many natural processes, such as those of complex system learning curves, exhibit a progression from small beginnings that accelerates and approaches a climax over time. When a specific mathematical model is lacking, a sigmoid function is often used.
The Hubbert curve [2] is the first derivative of a logistic function, which has been used for modeling the depletion of crude oil in particular, the depletion of finite mineral resources in general [3] and also population growth patterns. [4] Example of a Hubbert Linearization on the US Lower-48 crude oil production.
These approximations are only valid near, but not at, the end point, and so the method differs from end point estimations by way of first- and second-derivative plots, which require data at the end point. Gran plots were originally devised for graphical determinations in pre-computer times, wherein an x-y plot on paper would be manually ...
The classical finite-difference approximations for numerical differentiation are ill-conditioned. However, if is a holomorphic function, real-valued on the real line, which can be evaluated at points in the complex plane near , then there are stable methods.
An illustration of the five-point stencil in one and two dimensions (top, and bottom, respectively). In numerical analysis, given a square grid in one or two dimensions, the five-point stencil of a point in the grid is a stencil made up of the point itself together with its four "neighbors".
The smoothed curve (red line) and 1st derivative (green) were calculated with 7-point cubic Savitzky–Golay filters. Linear interpolation of the first derivative values at positions either side of the zero-crossing gives the position of the peak maximum. 3rd derivatives can also be used for this purpose. Location of an end-point in a titration ...
Inflection points in differential geometry are the points of the curve where the curvature changes its sign. [2] [3] For example, the graph of the differentiable function has an inflection point at (x, f(x)) if and only if its first derivative f' has an isolated extremum at x. (this is not the same as saying that f has an extremum).