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A typical titration curve of a diprotic acid, oxalic acid, titrated with a strong base, sodium hydroxide.Both equivalence points are visible. Titrations are often recorded on graphs called titration curves, which generally contain the volume of the titrant as the independent variable and the pH of the solution as the dependent variable (because it changes depending on the composition of the ...
These approximations are only valid near, but not at, the end point, and so the method differs from end point estimations by way of first- and second-derivative plots, which require data at the end point. Gran plots were originally devised for graphical determinations in pre-computer times, wherein an x-y plot on paper would be manually ...
The smoothed curve (red line) and 1st derivative (green) were calculated with 7-point cubic Savitzky–Golay filters. Linear interpolation of the first derivative values at positions either side of the zero-crossing gives the position of the peak maximum. 3rd derivatives can also be used for this purpose. Location of an end-point in a titration ...
The Hubbert curve [2] is the first derivative of a logistic function, which has been used for modeling the depletion of crude oil in particular, the depletion of finite mineral resources in general [3] and also population growth patterns. [4] Example of a Hubbert Linearization on the US Lower-48 crude oil production.
An illustration of the five-point stencil in one and two dimensions (top, and bottom, respectively). In numerical analysis, given a square grid in one or two dimensions, the five-point stencil of a point in the grid is a stencil made up of the point itself together with its four "neighbors".
The first potentiometric titration was carried out in 1893 by Robert Behrend at Ostwald's Institute in Leipzig. He titrated mercurous solution with potassium chloride, potassium bromide, and potassium iodide. He used a mercury electrode along with a mercury/mercurous nitrate reference electrode. He found that in a cell composed of mercurous ...
The derivative of () at the point = is the slope of the tangent to (, ()). [3] In order to gain an intuition for this, one must first be familiar with finding the slope of a linear equation, written in the form = +. The slope of an equation is its steepness.
Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...