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The production of polyethylene glycol was first reported in 1859. Both A. V. Lourenço and Charles Adolphe Wurtz independently isolated products that were polyethylene glycols. [52] Polyethylene glycol is produced by the interaction of ethylene oxide with water, ethylene glycol, or ethylene glycol oligomers. [53]
Polyethylene glycol. PEGylation (or pegylation) is the process of both covalent and non-covalent attachment or amalgamation of polyethylene glycol (PEG, in pharmacy called macrogol) polymer chains to molecules and macrostructures, such as a drug, therapeutic protein or vesicle, which is then described as PEGylated.
Ethylene glycol is widely used to inhibit the formation of natural gas clathrates (hydrates) in long multiphase pipelines that convey natural gas from remote gas fields to a gas processing facility. Ethylene glycol can be recovered from the natural gas and reused as an inhibitor after purification treatment that removes water and inorganic salts.
Polyethylene was first synthesized by the German chemist Hans von Pechmann, who prepared it by accident in 1898 while investigating diazomethane. [12] [a] [13] [b] When his colleagues Eugen Bamberger and Friedrich Tschirner characterized the white, waxy substance that he had created, they recognized that it contained long −CH 2 − chains and termed it polymethylene.
Polyols may be classified according to their chemistry. [5] Some of these chemistries are polyether, polyester, [6] polycarbonate [7] [8] and also acrylic polyols. [9] [10] Polyether polyols may be further subdivided and classified as polyethylene oxide or polyethylene glycol (PEG), polypropylene glycol (PPG) and Polytetrahydrofuran or PTMEG.
The Selexol process is similar to the Rectisol process, which uses refrigerated methanol as the solvent. The Selexol solvent is a mixture of the dimethyl ethers of polyethylene glycol. Selexol is a physical solvent, unlike amine based acid gas removal solvents that rely on a chemical reaction with the acid gases. Since no chemical reactions are ...