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2, has zero dipole moment, while near the other extreme, gas phase potassium bromide, KBr, which is highly ionic, has a dipole moment of 10.41 D. [9] [page needed] [10] [verification needed] For polyatomic molecules, there is more than one bond. The total molecular dipole moment may be approximated as the vector sum of the individual bond ...
Atomic charges for a given compound can be derived in multiple ways, such as: extracted from electron densities measured using high resolution x-ray, gamma ray, or electron beam diffraction experiments; measured dipole moments; the Extended Born thermodynamic cycle, including an analysis of covalent and ionic bonding contributions
A stronger mathematical definition is to use vector algebra, since a quantity with magnitude and direction, like the dipole moment of two point charges, can be expressed in vector form = where d is the displacement vector pointing from the negative charge to the positive charge. The electric dipole moment vector p also points from the negative ...
The polarizability of an atom or molecule is defined as the ratio of its induced dipole moment to the local electric field; in a crystalline solid, one considers the dipole moment per unit cell. [1] Note that the local electric field seen by a molecule is generally different from the macroscopic electric field that would be measured externally.
In most dipolar compounds the charges are delocalized. [1] Unlike salts, dipolar compounds have charges on separate atoms, not on positive and negative ions that make up the compound. Dipolar compounds exhibit a dipole moment. Dipolar compounds can be represented by a resonance structure.
Typical dipole moments for simple diatomic molecules are in the range of 0 to 11 D. Molecules with symmetry point groups or containing inversion symmetry will not have a permanent dipole moment, while highly ionic molecular species have a very large dipole moment, e.g. gas-phase potassium bromide, KBr, with a dipole moment of 10.41 D. [3] A proton and an electron 1 Å apart have a dipole ...
Molecular symmetry in physics and chemistry describes the symmetry present in molecules and the classification of molecules according to their symmetry. Molecular symmetry is a fundamental concept in the application of quantum mechanics in physics and chemistry, for example, it can be used to predict or explain many of a molecule's properties, such as its dipole moment and its allowed ...
Transition dipole moment, the electrical dipole moment in quantum mechanics; Molecular dipole moment, the electric dipole moment of a molecule; Bond dipole moment, the measure of polarity of a chemical bond; Electron electric dipole moment, the measure of the charge distribution within an electron; Magnetic dipole moment, the measure of the ...