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[15] [16] The term "methyl" was derived in about 1840 by back-formation from "methylene", and was then applied to describe "methyl alcohol" (which since 1892 is called "methanol"). Methyl is the IUPAC nomenclature of organic chemistry term for an alkane (or alkyl) molecule, using the prefix "meth-" to indicate the presence of a single carbon.
Many of methylene's electronic states lie relatively close to each other, giving rise to varying degrees of radical chemistry. The ground state is a triplet radical with two unpaired electrons ( X ̃ 3 B 1 ), [ 10 ] and the first excited state is a singlet non-radical ( ã 1 A 1 ).
The hexamethylene diamine molecule contains six methylene groups. A methylene group is any part of a molecule that consists of two hydrogen atoms bound to a carbon atom, which is connected to the remainder of the molecule by two single bonds. [1] The group may be represented as −CH 2 − or >CH 2, where the '>' denotes the two bonds.
Etymologically, the word methane is coined from the chemical suffix "-ane", which denotes substances belonging to the alkane family; and the word methyl, which is derived from the German Methyl (1840) or directly from the French méthyle, which is a back-formation from the French méthylène (corresponding to English "methylene"), the root of ...
The methyl "substituent" or "group" is highlighted red. According to the usual rules of nomenclature, alkyl groups are included in the name of the molecule before the root, as in methylpentane. This name is, however, ambiguous, as the methyl branch could be on various carbon atoms.
Methylation, in the chemical sciences, is the addition of a methyl group on a substrate, or the substitution of an atom (or group) by a methyl group. Methylation is a form of alkylation, with a methyl group replacing a hydrogen atom. These terms are commonly used in chemistry, biochemistry, soil science, and biology.
Methylene may refer to: Methylene group or methylene bridge (CH 2 < or equivalently -CH 2-), a part of a molecule connected to the rest of the molecule by two single bonds. An older name for methylidene (=CH 2), a part of a molecule connected to another atom by a double bond. Methylene (compound) (CH 2), an organic compound.
Upon treatment with an alcohol, it converts to methane and either an alkoxy or hydroxyalkyl. Reduction of methyl gives methane. When heated above, at most, 1,400 °C (1,700 K), methyl decomposes to produce methylidyne and elemental hydrogen, or to produce methylene and atomic hydrogen: CH • 3 → CH • + H 2 CH • 3 → CH • 2 + H •