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When atmospheric carbon dioxide (CO 2), or carbonate ions (HCO − 3, CO 2− 3 dissolved in water) diffuse into concrete from its external surface, they react with calcium hydroxide (portlandite, Ca(OH) 2) and the pH of the concrete pore water progressively decreases from 13.5 – 12.5 to 8.5 (pH of water in equilibrium with calcite).
Contact with wet concrete can cause skin chemical burns due to the caustic nature of the mixture of cement and water (including rainwater). Indeed, the pH of fresh cement water is highly alkaline due to the presence of free potassium and sodium hydroxides in solution (pH ~ 13.5). Eyes, hands and feet must be correctly protected to avoid any ...
Aqion is a hydrochemistry software tool. It bridges the gap between scientific software (such like PhreeqC [1]) and the calculation/handling of "simple" water-related tasks in daily routine practice.
This reaction is accompanied by hydration and swelling of the alkali gel leading to the expansion of the affected aggregates. The pH of the fresh alkali gel is very high and it has often a characteristic amber color. The high pH of young alkali gel exudations often precludes the growth of mosses at the surface of concrete crack infilling. 2.
Calculation of the true sorptivity required numerical iterative procedures dependent on soil water content and diffusivity. John R. Philip (1969) showed that sorptivity can be determined from horizontal infiltration where water flow is mostly controlled by capillary absorption: I = S t {\displaystyle I=S{\sqrt {t}}} where S is sorptivity and I ...
A w/c ratio higher than 0.60 is not acceptable as fresh concrete becomes "soup" [2] and leads to a higher porosity and to very poor quality hardened concrete as publicly stated by Prof. Gustave Magnel (1889-1955, Ghent University, Belgium) during an official address to American building contractors at the occasion of one of his visits in the ...
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