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For groundwater "potentiometric surface" is a synonym of "piezometric surface" which is an imaginary surface that defines the level to which water in a confined aquifer would rise were it completely pierced with wells. [1] If the potentiometric surface lies above the ground surface, a flowing artesian well results.
In fact, since the potentiometric measurement is a non-destructive measurement, assuming that the electrode is in equilibrium with the solution, we are measuring the solution's potential. Potentiometry usually uses indicator electrodes made selectively sensitive to the ion of interest, such as fluoride in fluoride selective electrodes , so that ...
Typically this equation is used to find the average T and S values near a pumping well, from drawdown data collected during an aquifer test. This is a simple form of inverse modeling, since the result ( s ) is measured in the well, r , t , and Q are observed, and values of T and S which best reproduce the measured data are put into the equation ...
An ion-selective electrode (ISE), also known as a specific ion electrode (SIE), is a simple membrane-based potentiometric device which measures the activity of ions in solution. [1] It is a transducer (or sensor) that converts the change in the concentration of a specific ion dissolved in a solution into an electrical potential. ISE is a type ...
The Gran plot is based on the Nernst equation which can be written as = + {+} where E is a measured electrode potential, E 0 is a standard electrode potential, s is the slope, ideally equal to RT/nF, and {H +} is the activity of the hydrogen ion.
In analytical chemistry, potentiometric titration is a technique similar to direct titration of a redox reaction. It is a useful means of characterizing an acid . No indicator is used; instead the electric potential is measured across the analyte , typically an electrolyte solution.
A metre bridge is a simple type of potentiometer which may be used in school science laboratories to demonstrate the principle of resistance measurement by potentiometric means. A resistance wire is laid along the length of a metre rule and contact with the wire is made through a galvanometer by a slider. When the galvanometer reads zero, the ...
The LAPS has several advantages over other types of chemical sensors. The sensor surface is completely flat, no structures, wiring or passivation are required. At the same time, the "light-addressability" of the LAPS makes it possible to obtain a spatially resolved map of the distribution of the ion concentration in the specimen.